Pairwise-interwoven R66(48) hexagonal nets in the hydrogen-bonded structure of hexamethylenetetramine-1,1,1-tris(4-hydroxyphenyl)ethane (1/1)

被引：21

作者：

Coupar, PI ^{[1
]}

Ferguson, G

Glidewell, C

Meehan, PR

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] Univ Guelph, Dept Chem & Biochem, Guelph, ON N1G 2W1, Canada

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S010827019701086X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the 1:1 adduct formed by hexamethylenetetramine (HMTA) and 1,1,1-tris(3-hydroxyphenyl)ethane, C6H12N4.C20H18O3, the tris-phenol acts as a triple donor of hydrogen bonds of type O-H ... N and the HMTA as a triple acceptor of such hydrogen bonds, with O ... N distances of 2.777(4), 2.781(4) and 7.795(3)Angstrom. The components are assembled into infinite nets comprising hexagonal rings, and pairs of such nets an interwoven; the pairs of interwoven nets are, in addition, connected by C-H ... O hydrogen bonds with a C ... O distance of 3.339(5)Angstrom.

引用

页码：1978 / 1980

页数：3

共 22 条

[1] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].

ALLEN, FH ;

KENNARD, O ;

WATSON, DG ;

BRAMMER, L ;

ORPEN, AG ;

TAYLOR, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19

[2] PATTERNS IN HYDROGEN BONDING - FUNCTIONALITY AND GRAPH SET ANALYSIS IN CRYSTALS [J].

BERNSTEIN, J ;

DAVIS, RE ;

SHIMONI, L ;

CHANG, NL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (15) :1555-1573

[3] HYDROGEN-BONDING IN ORGANOMETALLIC CRYSTALS .2. C-H-CENTER-DOT-CENTER-DOT-CENTER-DOT-O HYDROGEN-BONDS IN BRIDGED AND TERMINAL FIRST-ROW METAL-CARBONYLS [J].

BRAGA, D ;

GREPIONI, F ;

BIRADHA, K ;

PEDIREDDI, VR ;

DESIRAJU, GR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (11) :3156-3166

[4] Crystal engineering using bisphenols and trisphenols. Complexes with hexamethylenetetramine (HMTA): Strings, multiple helices and chains-of-rings in the crystal structures of the adducts of HMTA with 4,4'-thiodiphenol(1/1), 4,4'-sulfonyldiphenol(1/1), 4,4'-isopropylidenediphenol(1/1), 1,1,1-tris(4-hydroxyphenyl)ethane(1/2) and 1,3,5-trihydroxybenzene(2/3) [J].

Coupar, PI ;

Glidewell, C ;

Ferguson, G .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1997, 53 :521-533

[5] THE C-H...O HYDROGEN-BOND IN CRYSTALS - WHAT IS IT [J].

DESIRAJU, GR .

ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (10) :290-296

[6] The C-H center dot center dot center dot O hydrogen bond: Structural implications and supramolecular design [J].

Desiraju, GR .

ACCOUNTS OF CHEMICAL RESEARCH, 1996, 29 (09) :441-449

[7] CRYSTAL STRUCTURE OF TRIMESIC ACID (BENZENE-1,3,5-TRICARBOXYLIC ACID) [J].

DUCHAMP, DJ ;

MARSH, RE .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1969, B 25 :5-&

[8]

*ENR NON, 1992, CAD 4 PC SOFTW VERS

[9] ENCODING AND DECODING HYDROGEN-BOND PATTERNS OF ORGANIC-COMPOUNDS [J].

ETTER, MC .

ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (04) :120-126

[10] Crystal engineering using trisphenols. Three-dimensional hydrogen-bonding networks in 1,1,1-tris(4-hydroxyphenyl)ethane, its hydrated adduct with 1,4-diazabicyclo[2.2.2]octane(1/1/1) and its adduct with piperazine(4/3) [J].

Ferguson, G ;

Bell, W ;

Coupar, PI ;

Glidewell, C .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1997, 53 :534-543

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