Stability of TiO2 hydrosols synthesized by hydrolysis of titanium tetraethoxide

被引:13
作者
Ghenne, E [1 ]
Dumont, F [1 ]
Buess-Herman, C [1 ]
机构
[1] Free Univ Brussels, Fac Sci CP 255, Chim Analyt Serv, B-1050 Brussels, Belgium
关键词
hydrolysis; hydrosol; stability; titanium dioxide; titanium tetraethoxide;
D O I
10.1016/S0927-7757(96)03958-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The TiO2 hydrosols studied in this work were synthesized by hydrolysis of titanium tetraethoxide according to Zukoski's method. Critical coagulation concentrations (CCC) were measured for pH values ranging from 2 to 12 in the presence of various monovalent ions. The observed ionic adsorption sequences are explained in terms of an extension of the Gurney concept of ion-ion interactions. The influence of the volume fraction of the solid is also reported and explained by the coagulation-repeptization theory. (C) 1998 Elsevier Science B.V.
引用
收藏
页码:63 / 67
页数:5
相关论文
共 10 条