[60]Fullerene-initiated bulk polymerization of N-vinylcarbazole under the microwave irradiation

被引：12

作者：

Chen, Y

Wang, JX

Zhang, DZ

Cai, RF ^{[1
]}

Yu, HX

Su, CW

Huang, ZE

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[2] E China Univ Sci & Technol, Dept Polymer Sci, Shanghai 200237, Peoples R China

来源：

POLYMER | 2000年 / 41卷 / 21期

基金：

中国国家自然科学基金;

关键词：

bulk polymerization; microwave irradiation; 60]fullerene;

D O I：

10.1016/S0032-3861(00)00188-9

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The [60]fullerene-initiated "charge-transfer" bulk polymerization reaction of N-vinylcarbazole (NVC) under microwave irradiation (490 W) has been demonstrated. In comparison with the C-60-initiated polymerization reaction of NVC in the water bath at 70 degrees C, carrying out the polymerization reaction in the microwave oven was found to be advantageous due to the remarkable decrease in the time necessary to carry out reaction, and to the considerable improvement in yield of poly(N-vinylcarbazole). A reasonable polymerization reaction pathway via C-60-NVC ion-radical pairs is suggested. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：7877 / 7880

页数：4

共 12 条

[1] Reactions of transition metal complexes with fullerenes (C60, C70, etc.) and related materials [J].