Bioinspired Peony-Like β-Ni(OH)2 Nanostructures with Enhanced Electrochemical Activity and Superhydrophobicity

被引:45
作者
Cao, Huaqiang [1 ]
Zheng, He [1 ,2 ]
Liu, Kaiyu [2 ]
Warner, Jamie H. [3 ]
机构
[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
[2] Cent S Univ, Sch Chem & Chem Engn, Changsha 410083, Peoples R China
[3] Univ Oxford, Dept Mat, Oxford OX1 3PH, England
基金
国家高技术研究发展计划(863计划); 中国国家自然科学基金;
关键词
biomimetic synthesis; hierarchical structure; nanostructures; self-assembly; superhydrophobic effect; ALPHA-NICKEL HYDROXIDE; NANOTECHNOLOGY; ARCHITECTURES; SURFACES; NANOWIRE;
D O I
10.1002/cphc.200900665
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Constructing complex nanostructures has become increasingly important in the development of hydrogen storage, self-cleaning materials, and the formation of chiral branched nanowires. Several approaches have been developed to generate complex nanostructures, which have led to novel applications. Combining biology and nanotechnology through the utilization of biomolecules to chemically template the growth of complex nanostructures during synthesis has aroused great interest. Herein, we use a biomolecule-assisted hydrothermal method to synthesize beta-phase Ni(OH)(2) peony-like complex nanostructures with second-order structure nanoplate structure. The novel beta-Ni(OH)(2) nanostructures exhibit high-power Ni/MH battery performance, close to the theoretical capacity of Ni(OH)(2), as well as controlled wetting behavior. We demonstrate that this bioinspired route to generate a complex nanostructure has applications in environmental protection and green secondary cells. This approach opens up opportunities for the synthesis and potential applications of new kinds of nanostructures.
引用
收藏
页码:489 / 494
页数:6
相关论文
共 38 条
[1]   Aggregation-based crystal growth and microstructure development in natural iron oxyhydroxide biomineralization products [J].
Banfield, JF ;
Welch, SA ;
Zhang, HZ ;
Ebert, TT ;
Penn, RL .
SCIENCE, 2000, 289 (5480) :751-754
[2]   Nucleic acid and nucleotide-mediated synthesis of inorganic nanoparticles [J].
Berti, Lorenzo ;
Burley, Glenn A. .
NATURE NANOTECHNOLOGY, 2008, 3 (02) :81-87
[3]   Self-cleaning surfaces - virtual realities [J].
Blossey, R .
NATURE MATERIALS, 2003, 2 (05) :301-306
[4]   PHOTOELECTROCHEMISTRY OF NICKEL-HYDROXIDE THIN-FILMS [J].
CARPENTER, MK ;
CORRIGAN, DA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (04) :1022-1026
[5]  
CLAYDEN J, 2001, ORGANIC CHEM, P69
[6]   Shaping crystals with biorriolecules [J].
De Yoreo, JJ ;
Dove, PM .
SCIENCE, 2004, 306 (5700) :1301-1302
[7]  
Hornyak G.L., 2008, INTRO NANOSCIENCE
[8]   Controllable Synthesis of Zinc-Substituted α- and β-Nickel Hydroxide Nanostructures and Their Collective Intrinsic Properties [J].
Hu, Bo ;
Chen, Shao-Feng ;
Liu, Shu-Juan ;
Wu, Qing-Song ;
Yao, Wei-Tang ;
Yu, Shu-Hong .
CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (29) :8928-8938
[9]   Synthesis of nanosized α-nickel hydroxide by a sonochemical method [J].
Jeevanandam, P ;
Koltypin, Y ;
Gedanken, A .
NANO LETTERS, 2001, 1 (05) :263-266
[10]   Synthesis of nanowire and mesoporous low-temperature LiCoO2 by a post-templating reaction [J].
Jiao, F ;
Shaju, KM ;
Bruce, PG .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (40) :6550-6553