Hierarchical self-assembly of one-dimensional streptavidin bundles as a collagen mimetic for the biomineralization of calcite

被引:91
作者
Burazerovic, Sabina [1 ]
Gradinaru, Julieta [1 ]
Pierron, Julien [1 ]
Ward, Thomas R. [1 ]
机构
[1] Univ Neuchatel, Inst Chem, CH-2009 Neuchatel, Switzerland
关键词
biomineralization; calcite; coordination polymers; metal-organic protein frameworks; protein structures;
D O I
10.1002/anie.200701080
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Bundle up: The introduction of streptavidin (as a linker) between two FeII(terpyridine-bis-biotin) connectors affords a one-dimensional metal-organic protein framework (MOPF). In the presence of calcium ions and CO2 vapors, these MOPF aggregates form protein bundles that template the biomineralization of calcite. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5510 / 5514
页数:5
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