Solvent roles in metal ion coordination:: the NiCl2O-solvates, NiCl2•4MeOH, NiCl2•2MeOH•0.5dioxan and NiCl2•2H2O•2dioxan

被引：5

作者：

Armanasco, NL ^{[1
]}

Baker, MV ^{[1
]}

Brown, DH ^{[1
]}

Harrowfield, JM ^{[1
]}

Skelton, BW ^{[1
]}

White, AH ^{[1
]}

机构：

[1] Univ Western Australia, Sch Biomed & Chem Sci, Crawley, WA 6009, Australia

来源：

INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 15期

关键词：

nickel(II) coordination; solvation; crystal structures;

D O I：

10.1016/j.ica.2004.07.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Low-temperature, single crystal X-ray structural characterisations of trans-[NiCl2(HOMe)(4)], trans-O-[Ni(MeOH)(2)-(mu-Cl)((2/2)2)]((x, x))(.)0.5dioxan and trans-trans-[Ni(H2O)(2)Cl-2(O-dioxan-O)((2/2))]((x,x))(.) dioxan are recorded, offering intriguing insights into O-donor/Ni(II) relativities. All nickel atoms in all structures are located on crystallographic inversion centres, the last two compounds being one-dimensional polymers. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：4562 / 4567

页数：6

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