Recent developments in the coordination chemistry of porphyrin complexes containing non-metallic and semimetallic elements

被引：37

作者：

Brothers, PJ ^{[1
]}

机构：

[1] Univ Auckland, Dept Chem, Auckland, New Zealand

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2002年 / 6卷 / 04期

关键词：

porphyrin; main group element; porphyrin ruffling; boron; tellurium; silicon; tin; phosphorus; arsenic; antimony;

D O I：

10.1142/S1088424602000294

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recent advances in the chemistry of main group porphyrin complexes are surveyed. New, unprecedented structural types for porphyrin complexes which have been revealed from the recent reports of boron and tellurium porphyrins are described. Advances in the preparation and reactivity of Group 14 (silicon and tin) and Group 15 porphyrin complexes are discussed. A systematic variation in the out-of-plane distortion (ruffling) of light element Group 14 and 15 porphyrin complexes has become apparent now that a significant number of structurally characterized examples are at hand. Copyright (C) 2002 Society of Porphyrins & Phthalocyanines.

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收藏

页码：259 / 267

页数：9

相关论文

共 56 条

[1] Metalloporphyrins as initiators for living and immortal polymerizations [J].

Aida, T ;

Inoue, S .

ACCOUNTS OF CHEMICAL RESEARCH, 1996, 29 (01) :39-48

[2] SYNTHESIS OF ANTIMONY(V) OCTAETHYLPORPHYRINS THAT CONTAIN A SIGMA-BONDED ELEMENT CARBON BOND [J].

AKIBA, KY ;

ONZUKA, Y ;

ITAGAKI, M ;

HIROTA, H ;

YAMAMOTO, Y .

ORGANOMETALLICS, 1994, 13 (07) :2800-2803

[3] Synthesis, structure, electrochemistry, and spectroelectrochemistry of hypervalent Phosphorus(V) octaethylporphyrins and theoretical analysis of the nature of the PO bond in P(OEP)(CH2CH3)(O) [J].

Akiba, KY ;

Nadano, R ;

Satoh, W ;

Yamamoto, Y ;

Nagase, S ;

Ou, ZP ;

Tan, XY ;

Kadish, KM .

INORGANIC CHEMISTRY, 2001, 40 (22) :5553-5567

[4]

[Anonymous], PORPHYRIN HDB

[5] TIN(IV) PORPHYRIN COMPLEXES .7. CRYSTAL-STRUCTURES OF MESO-TETRAPHENYL-PORPHYRINATOTIN(IV) DIFLUORIDE AND DINITRATE, AND THE CORRELATION OF SPECTROSCOPIC DATA WITH CORE SIZE FOR TIN(IV) PORPHYRIN COMPLEXES [J].

ARNOLD, DP ;

TIEKINK, ERT .

POLYHEDRON, 1995, 14 (13-14) :1785-1789

[6] SYNTHESIS AND CHARACTERIZATION OF LITHIUM, SODIUM, AND POTASSIUM PORPHYRIN COMPLEXES - X-RAY CRYSTAL-STRUCTURES OF LI2(C6H12O2)2TMPP, NA2(THF)4OEP, AND K2(PYRIDINE)4OEP [J].

ARNOLD, J ;

DAWSON, DY ;

HOFFMAN, CG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (07) :2707-2713

[7] THE 1ST STRUCTURALLY CHARACTERIZED ALKALI-METAL PORPHYRIN - LI-7 NMR BEHAVIOR AND X-RAY CRYSTAL-STRUCTURE OF THE DILITHIUM SALT OF OCTAETHYLPORPHYRIN(2-) [J].

ARNOLD, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (14) :976-978

[8]

Arnold J., 1999, PORPHYRIN HDB, V3, P113

[9]

Belcher WJ, 1998, ANGEW CHEM INT EDIT, V37, P1112, DOI 10.1002/(SICI)1521-3773(19980504)37:8<1112::AID-ANIE1112>3.0.CO

[10]

2-Q

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