A convergent coordination chemistry-based approach to dissymmetric macrocyclic cofacial porphyrin complexes

被引：26

作者：

Oliveri, Christopher G.

Heo, Jungseok

Nguyen, SonBinh T.

Mirkin, Chad A.

Wawrzak, Zdzislaw

机构：

[1] Northwestern Univ, Dept Chem, Int Inst Nanotechnol, Evanston, IL 60208 USA

[2] Northwestern Univ, Dept Biochem & Mol Biol & Cell Biol, Evanston, IL 60208 USA

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 19期

关键词：

D O I：

10.1021/ic701424j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report a highly convergent and modular approach for the synthesis of dissymmetric cofacial porphyrin complexes, which is based upon the weak-link approach to supramolecular coordination chemistry. Specifically, we have utilized a halide-induced ligand rearrangement reaction, which is capable of providing heteroligated mixed-metal porphyrin complexes in quantitative yield. Significantly, the adoption of a coordination chemistry based approach for the synthesis of these complexes allows for facile in situ regulation of the porphyrin-porphyrin interactions through the addition of external chemical stimuli.

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页码：7716 / 7718

页数：3

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