Direct observation of perchlorate incorporation induced by redox reaction of ferrocene terminated self-assembled monolayer studied by in situ FT-surface enhanced Raman spectroscopy

被引：28

作者：

Nishiyama, K ^{[1
]}

Ueda, A ^{[1
]}

Tanoue, S ^{[1
]}

Koga, T ^{[1
]}

Taniguchi, I ^{[1
]}

机构：

[1] Kumamoto Univ, Fac Engn, Dept Appl Chem & Biochem, Kumamoto 8608555, Japan

来源：

CHEMISTRY LETTERS | 2000年 / 08期

关键词：

D O I：

10.1246/cl.2000.930

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The incorporation of ClO4- into 8-ferrocenyloctanethiol (8FT) self-assembled monolayer (SAM) induced by the redox reaction at a gold wire electrode was demonstrated using in situ FT Raman spectroelectochemistry. Upon oxidation of the 8FT SAM, a band attributed to ClO4- was clearly observed and the band disappeared in its reduced state. On the other hand, when HNO3 was used as a supporting electrolyte, the band attributed to NO3- was not observed In the oxidized form of 8FT.

引用

页码：930 / 931

页数：2

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