Singlet and triplet energy transfer processes in ruthenium(II) bipyridine complexes containing covalently bound

被引：70

作者：

Wilson, GJ

Sasse, WHF

Mau, AWH

机构：

[1] CSIRO, Division of Chemicals and Polymers, Rosebank MDC, Clayton, Vic. 3169

来源：

CHEMICAL PHYSICS LETTERS | 1996年 / 250卷 / 5-6期

关键词：

D O I：

10.1016/0009-2614(96)00056-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Singlet and tripler energy transfer processes in [Ru(bipy)(2)(4-methyl-4'-(2-arylethyl)-2,2'-bipyridine)](2+) have been investigated, where aryl = 2-naphthyl (Ru-Naph), 9-anthryl (Ru-Anth) and 1-pyrenyl (Ru-Pyrene). In each case fluorescence from the aromatic chromophore is quenched by intramolecular energy transfer to Ru(bipy)(3)(2+) whereas emission from the Ru(bipy)(3)(2+) moiety is controlled by the relative energy of its (3)MLCT state and the pendant arene tripler states, Consequently (3)MLCT emission is observed for Ru-Naph whereas it is fully quenched for Ru-Anth. When the two states are isoenergetic (e.g. Ru-Pyrene) a long-lived (3)MLCT emission is observed which decays with the same lifetime as the pyrene tripler state (5.23 mu s).

引用

页码：583 / 588

页数：6

共 27 条

[1] BALZANI V, 1987, NATO ASI SERIES C, V214
[2] Balzani V.S. F., 1991, Supramolecular Photochemistry
[3] RIGID ROD-LIKE DINUCLEAR RU(II) OS(II) TERPYRIDINE-TYPE COMPLEXES - ELECTROCHEMICAL-BEHAVIOR, ABSORPTION-SPECTRA, LUMINESCENCE PROPERTIES, AND ELECTRONIC-ENERGY TRANSFER THROUGH PHENYLENE BRIDGES
BARIGELLETTI, F
FLAMIGNI, L
BALZANI, V
COLLIN, JP
SAUVAGE, JP
SOUR, A
CONSTABLE, EC
THOMPSON, AMWC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (17) : 7692 - 7699
[4] LUMINESCENCE PROPERTIES OF RIGID ROD-LIKE BINUCLEAR RUTHENIUM(II)-OSMIUM(II) TERPYRIDINE COMPLEXES - ELECTRONIC INTERACTION THROUGH PHENYL BRIDGES
BARIGELLETTI, F
FLAMIGNI, L
BALZANI, V
COLLIN, JP
SAUVAGE, JP
SOUR, A
CONSTABLE, EC
THOMPSON, AMWC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (11) : 942 - 944
[5] ELECTRONIC-ENERGY TRANSFER IN A SUPRAMOLECULAR SPECIES CONTAINING THE [RU(BPY)(3)](2+), [OS(BPY)(3)](2+), AND ANTHRACENE CHROMOPHORIC UNITS
BELSER, P
DUX, R
BAAK, M
DECOLA, L
BALZANI, V
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (05) : 595 - 598
[6] INTRAMOLECULAR ENERGY-TRANSFER IN A CHROMOPHORE QUENCHER COMPLEX
BOYDE, S
STROUSE, GF
JONES, WE
MEYER, TJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (19) : 7448 - 7454
[7] LIFETIMES, SPECTRA, AND QUENCHING OF THE EXCITED-STATES OF POLYPYRIDINE COMPLEXES OF IRON(II), RUTHENIUM(II), AND OSMIUM(II)
CREUTZ, C
CHOU, M
NETZEL, TL
OKUMURA, M
SUTIN, N
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (04) : 1309 - 1319
[8] PHOTOCHEMICALLY INDUCED CHARGE SEPARATION AT THE MOLECULAR-LEVEL - A CHROMOPHORE QUENCHER COMPLEX CONTAINING BOTH AN ELECTRON-TRANSFER DONOR AND AN ACCEPTOR
DANIELSON, E
ELLIOTT, CM
MERKERT, JW
MEYER, TJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (08) : 2519 - 2520
[9] PHOTOINDUCED ENERGY AND ELECTRON-TRANSFER PROCESSES IN SUPRAMOLECULAR SPECIES - TRIS(BIPYRIDINE) COMPLEXES OF RU(II)/OS(II), RU(II)/RU(III), OS(II)/OS(III), AND RU(II)/OS(III) SEPARATED BY A RIGID SPACER
DECOLA, L
BALZANI, V
BARIGELLETTI, F
FLAMIGNI, L
BELSER, P
VONZELEWSKY, A
FRANK, M
VOGTLE, F
[J]. INORGANIC CHEMISTRY, 1993, 32 (23) : 5228 - 5238
[10] EDEL A, 1984, NOUV J CHIM, V8, P495

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