Symmetry rules and reaction mechanisms of Ziegler-Natta catalysts

被引：58

作者：

Ewen, JA ^{[1
]}

机构：

[1] Catalyst Res Corp, Houston, TX 77059 USA

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1998年 / 128卷 / 1-3期

关键词：

D O I：

10.1016/S1381-1169(97)00167-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Symmetry rules obeyed by metallocenes having well-defined, rigid structures are in accord with reaction mechanisms proposed in the 1960s and 1970s for Ziegler-Natta catalysts with unknown structures. (C) 1998 Elsevier Science B.V.

引用

页码：103 / 109

页数：7

共 46 条

[1]

ALLEGRA G, 1971, MAKROMOLEKUL CHEM, V145, P235

[2]

AMMENDOLA P, 1984, MAKROMOL CHEM, V185, P2421

[3] ZIEGLER-NATTA CATALYSIS .3. STEREOSPECIFIC POLYMERIZATION OF PROPENE WITH THE CATALYST SYSTEM TICL3-ALET3 [J].

ARLMAN, EJ ;

COSSEE, P .

JOURNAL OF CATALYSIS, 1964, 3 (01) :99-104

[4]

Boor J., 1979, Ziegler-Natta Catalysts and Polymerization

[5]

CAVALLO L, 1989, POLYM COMMUN, V30, P16

[6]

CAVALLO L, 1990, POLYMER, V31, P580

[7]

CORRADINI P, 1988, GAZZ CHIM ITAL, V118, P173

[8]

CORRADINI P, 1995, ZIEGLER CATALYSTS, P237

[9] ANALYSIS OF MODELS FOR THE ZIEGLER-NATTA STEREOSPECIFIC POLYMERIZATION ON THE BASIS OF NON-BONDED INTERACTIONS AT THE CATALYTIC SITE .1. COSSEE MODEL [J].

CORRADINI, P ;

BARONE, V ;

FUSCO, R ;

GUERRA, G .

EUROPEAN POLYMER JOURNAL, 1979, 15 (12) :1133-1141

[10]

CORRADINI P, 1989, WORKSH PRES STAT TRE

← 1 2 3 4 5 →