Fast exciton migration in porphyrin-functionalized polypeptides

被引:31
作者
Fujitsuka, M
Hara, M
Tojo, S
Okada, A
Troiani, V
Solladié, N
Majima, T
机构
[1] Osaka Univ, Inst Sci & Ind Res, SANKEN, Ibaraki, Osaka 5670047, Japan
[2] Univ Strasbourg 1, CNRS, Lab Electrochim & Chim Phys Corps Solide, Grp Synth Syst Porphyrin, F-67000 Strasbourg, France
关键词
D O I
10.1021/jp044866t
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The photophysical properties Of L-lysine-based polypeptides bearing porphyrin pendants were investigated. The intramolecular exciton-exciton annihilation resulting from the exciton migration among the porphyrin units deactivates the singlet excited state efficiently. It was revealed that the rate of the exciton migration depends on the polymerization degree.
引用
收藏
页码:33 / 35
页数:3
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