Sulphur poisoning of nickel-based hot gas cleaning catalysts in synthetic gasification gas - I. Effect of different process parameters

The effect of different process parameters on sulphur poisoning of nickel catalysts in tar (toluene), ammonia and methane decomposition was studied. Tests were carried out in a fixed-bed tube reactor at 800-1000 degrees C at 5 and under 20 bar total pressure using a synthetic gasification gas mixture. In the same conditions, sulphur affected less the toluene and methane decomposing activity than the ammonia decomposing activity. Ammonia conversion was affected by the catalyst type but not by the nickel content of catalyst. When temperature was increased the effect of sulphur poisoning was decreased. At 20 bar pressure the poisoning effect of sulphur was stronger than at 5 bar pressure. To prevent sulphur poisoning of nickel catalysts in the tar and ammonia decomposition process at high pressure (20-30 bar), the catalyst process should operate at > 900 degrees C. In addition, by decreasing the space velocity of the process the sulphur poisoning effect could be compensated in the test conditions. (C) 1997 Elsevier Science B.V.