Investigation of the specific adsorption of sulfate ions on powdered TiO2

被引:27
作者
Horányi, G [1 ]
机构
[1] Hungarian Acad Sci, Chem Res Ctr, Inst Chem, H-1525 Budapest, Hungary
基金
匈牙利科学研究基金会;
关键词
specific adsorption; sulfated; TiO2 (anatase); radiotracer technique;
D O I
10.1016/S0021-9797(03)00084-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The specific adsorption of radiolabeled sulfate ions from perchlorate supporting electrolyte onto TiO2 powder (anatase) has been investigated. The pH and concentration dependence of the adsorption was determined. Langmuir-like adsorption behavior similar to that on other oxides was found. From the pH dependence it follows that the protonation of the surface should precede the specific anion adsorption. The results obtained are compared with those reported for TiO2. bulk electrodes. (C) 2003 Elsevier Science (USA). All rights reserved.
引用
收藏
页码:580 / 583
页数:4
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