Detection of heavy metal ions in drinking water using a high-resolution differential surface plasmon resonance sensor

被引:221
作者
Forzani, ES
Zhang, HQ
Chen, W
Tao, NJ [1 ]
机构
[1] Arizona State Univ, Dept Elect Engn, Tempe, AZ 85287 USA
[2] Arizona State Univ, Ctr Solid State Elect Res, Tempe, AZ 85287 USA
[3] Univ Calif Riverside, Dept Chem & Environm Engn, Riverside, CA 92521 USA
关键词
D O I
10.1021/es049234z
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
We have built a high-resolution differential surface plasmon resonance (SPR) sensor for heavy metal ion detection. The sensor surface is divided into a reference and sensing areas, and the difference in the SPR angles from the two areas is detected with a quadrant cell photodetector as a differential signal. In the presence of metal ions, the differential signal changes due to specific binding of the metal ions onto the sensing area coated with properly selected peptides, which provides an accurate real-time measurement and quantification of the metal ions. Selective detection of CU2+ and Ni2+ in the ppt-ppb range was achieved by coating the sensing surface with peptides NH2Gly-Gly-His-COOH and NH2-(HiS)(6)-COOH. CU2+ in drinking water was tested using this sensor.
引用
收藏
页码:1257 / 1262
页数:6
相关论文
共 25 条
  • [1] [Anonymous], NUCL ACIDS RES
  • [2] Arsenic speciation and reactivity in poultry litter
    Arai, Y
    Lanzirotti, A
    Sutton, S
    Davis, JA
    Sparks, DL
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2003, 37 (18) : 4083 - 4090
  • [3] Quaternary structure of α-crystallin is necessary for the binding of unfolded proteins:: A surface plasmon resonance study
    Avilov, SV
    Aleksandrova, NA
    Demchenko, AP
    [J]. PROTEIN AND PEPTIDE LETTERS, 2004, 11 (01) : 41 - 48
  • [4] Remote stripping analysis of lead and copper by a mercury-coated platinum microelectrode
    Baldo, MA
    Daniele, S
    Ciani, I
    Bragato, C
    Wang, J
    [J]. ELECTROANALYSIS, 2004, 16 (05) : 360 - 366
  • [5] Bannon DI, 2001, CLIN CHEM, V47, P1703
  • [6] ZP4, an improved neuronal Zn2+ sensor of the Zinpyr family
    Burdette, SC
    Frederickson, CJ
    Bu, WM
    Lippard, SJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (07) : 1778 - 1787
  • [7] CHINYAO EW, 1996, INT J DERMATOL, V35, P1
  • [8] Development and validation of a one-step immunoassay for determination of cadmium in human serum
    Darwish, IA
    Blake, DA
    [J]. ANALYTICAL CHEMISTRY, 2002, 74 (01) : 52 - 58
  • [9] A selective, ratiometric fluorescent sensor for Pb2+
    Deo, S
    Godwin, HA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (01) : 174 - 175
  • [10] Analysis of waste water by x-ray fluorescence spectrometry
    Eksperiandova, LP
    Blank, AB
    Makarovskaya, YN
    [J]. X-RAY SPECTROMETRY, 2002, 31 (03) : 259 - 263