Small-angle neutron scattering studies of sodium dodecyl sulfate interactions with gelatin .2. Effect of temperature and pH

被引:24
作者
Cosgrove, T
White, SJ
Zarbakhsh, A
Heenan, RK
Howe, AM
机构
[1] RUTHERFORD APPLETON LAB,DIDCOT OX11 0QS,OXON,ENGLAND
[2] KODAK EUROPEAN RES,HARROW HA1 4TY,MIDDX,ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1996年 / 92卷 / 04期
关键词
D O I
10.1039/ft9969200595
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Structural perturbations and interactions between the anionic surfactant sodium dodecyl sulfate (SDS) and the biopolymer and polyampholyte gelatin, have been studied using small-angle neutron scattering. The effects of temperature and changes in pH have been investigated. Although the physical properties of the systems change dramatically with temperature, from a gel at 25 degrees C to a fluid at 65 degrees C, the effects on the structure over the dimensions probed by small-angle neutron scattering are rather weak. Changes in pH, which alter the net charge of the gelatin, lead to dramatic changes in the scattering for pure gelatin solutions and for surfactant-gelatin mixtures.
引用
收藏
页码:595 / 599
页数:5
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