Supramolecular assembly of poly(phenylene vinylene) with crown ether substituents to form nanoribbons

被引：41

作者：

Luo, YH

Liu, HW

Xi, F

Li, L ^{[1
]}

Jin, XG

Han, CC

Chan, CM

机构：

[1] Chinese Acad Sci, Joint Lab Polymer Sci & Mat, State Key Lab Polymer Phys & Chem, Inst Chem, Beijing 100080, Peoples R China

[2] Hong Kong Univ Sci & Technol, Dept Chem Engn, Hong Kong, Hong Kong, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 21期

关键词：

D O I：

10.1021/ja0297739

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Poly(para-phenylene vinylene) with crown ether substituents (C-PPV) could form nanoribbons through supramolecular assembly with K+ in dilute chloroform solution. The length of the nanoribbons increased with an increase in the standing time of the C-PPV/K+ solution. Experimental evidence to support the interaction between K+ and crown ether substituents was provided, and the growth mechanism of C-PPWK+ nanorods to nanoribbons was proposed. The influence of the length of the nanoribbons on the photophysics of C-PPV was also investigated.

引用

页码：6447 / 6451

页数：5

共 33 条

[1]

An KH, 2001, ADV MATER, V13, P497, DOI 10.1002/1521-4095(200104)13:7<497::AID-ADMA497>3.0.CO

[2]

2-H

[3]

Bernius MT, 2000, ADV MATER, V12, P1737, DOI 10.1002/1521-4095(200012)12:23<1737::AID-ADMA1737>3.0.CO

[4]

2-N

[5] Photoluminescence in pyridine-based polymers: Role of aggregates [J].

Blatchford, JW ;

Jessen, SW ;

Lin, LB ;

Gustafson, TL ;

Fu, DK ;

Wang, HL ;

Swager, TM ;

MacDiarmid, AG ;

Epstein, AJ .

PHYSICAL REVIEW B, 1996, 54 (13) :9180-9189

[6] Spatially and temporally resolved emission from aggregates in conjugated polymers [J].

Blatchford, JW ;

Gustafson, TL ;

Epstein, AJ ;

VandenBout, DA ;

Kerimo, J ;

Higgins, DA ;

Barbara, PF ;

Fu, DK ;

Swager, TM ;

MacDiarmid, AG .

PHYSICAL REVIEW B, 1996, 54 (06) :R3683-R3686

[7] SCANNING FORCE MICROSCOPY IN BIOLOGY [J].

BUSTAMANTE, C ;

KELLER, D .

PHYSICS TODAY, 1995, 48 (12) :32-38

[8]

CHAN CM, 1994, POLYM SURFACE MODIFC

[9] Indium phosphide nanowires as building blocks for nanoscale electronic and optoelectronic devices [J].

Duan, XF ;

Huang, Y ;

Cui, Y ;

Wang, JF ;

Lieber, CM .

NATURE, 2001, 409 (6816) :66-69

[10] Electroluminescence in conjugated polymers [J].

Friend, RH ;

Gymer, RW ;

Holmes, AB ;

Burroughes, JH ;

Marks, RN ;

Taliani, C ;

Bradley, DDC ;

Dos Santos, DA ;

Brédas, JL ;

Lögdlund, M ;

Salaneck, WR .

NATURE, 1999, 397 (6715) :121-128

← 1 2 3 4 →