Narrower Bands with Better Charge Transport: The Counterintuitive Behavior of Semiconducting Copolymers

被引：29

作者：

Fornari, Rocco P. ^{[1
,2
]}

Troisi, Alessandro ^{[1
,2
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

[2] Univ Warwick, Ctr Sci Comp, Coventry CV4 7AL, W Midlands, England

来源：

ADVANCED MATERIALS | 2014年 / 26卷 / 45期

基金：

欧洲研究理事会;

关键词：

DISORDERED CONJUGATED POLYMERS; FIELD-EFFECT TRANSISTORS; ELECTRONIC-PROPERTIES; MOBILITY; MOTION; CHAIN;

D O I：

10.1002/adma.201402941

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The narrower bands formed by donor-acceptor polymers are not detrimental to transport, as the reduced electronic coupling along the chain is more than compensated by a reduced activation energy for transport. These polymers are less sensitive to the conformational disorder of the chain as long as the bandwidth is larger than a threshold. (Graph Presented). © 2014 Wiley-VCH Verlag GmbH & Co. KGaA.

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收藏

页码：7627 / 7631

页数：5

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