Enantio- and regioselective Heck-type reaction of arylboronic acids with 2,3-dihydrofuran

被引：36

作者：

Penn, Liza ^{[1
]}

Shpruhman, Alina ^{[1
]}

Gelman, Dmitri ^{[1
]}

机构：

[1] Hebrew Univ Jerusalem, Dept Organ Chem, IL-91904 Jerusalem, Israel

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 10期

关键词：

D O I：

10.1021/jo070170v

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Reported herein is a protocol for the enantioselective Pd(II)-catalyzed Heck-type reaction between arylboronic acids and 2,3-dihydrofuran. The highest chemical and optical yields were obtained when a Pd(OAc)(2)/(R)-MeO(biphenylphosphine) or a Pd(OAc)(2)/(R)-(2,2'-bis(diphenylphosphino)-1,1'-binaphthyl) catalyst and a Cu(OAc)(2) reoxidant were employed.

引用

页码：3875 / 3879

页数：5

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