Liquid-crystalline [60]fullerene-TTF dyads

被引：43

作者：

Allard, E

Oswald, F

Donnio, B

Guillon, D

Delgado, JL

Langa, F

Deschenaux, R

机构：

[1] Univ Neuchatel, Inst Chim, CH-2007 Neuchatel, Switzerland

[2] Inst Phys & Chim Mat Strasbourg, Grp Mat Organ, F-67034 Strasbourg 2, France

[3] Univ Castilla La Mancha, Fac Ciencias Medio Ambiente, Toledo 45071, Spain

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 03期

关键词：

D O I：

10.1021/ol047829t

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[60]Fullerene was functionalized with a TTF derivative and a bis-mesogenic fragment. The synthetic methodology was based on the addition of a malonate derivative to C(60) (Bingel-type reaction). Both the malonate and dyad showed smectic B and A phases. The supramolecular organization within the smectic layers was of the monolayer type for the malonate and of the bilayer type for the fullerene derivative. In the latter case, the supramolecular organization was governed by the C(60) unit.

引用

页码：383 / 386

页数：4

共 46 条

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