Nanoprocessing based on bicontinuous microdomains of block copolymers: Nanochannels coated with metals

被引：183

作者：

Hashimoto, T

Tsutsumi, K

Funaki, Y

机构：

[1] ERATO, Hashimoto Polymer Phasing Project, JST, Sakyo Ku, Kyoto 606, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Kyoto 60601, Japan

来源：

LANGMUIR | 1997年 / 13卷 / 26期

关键词：

D O I：

10.1021/la970967p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel process to produce a nanochannel comprised of a void in a polymer matrix is reported. The processing involves a selective degradation of one of the bicontinuous microdomain phases of microphase-separated block copolymers to create a continuous, tortuous hole having a diameter of nanometer scale (nanochannel) and plating of the surfaces with nickel metal. The nanochannel and the metal plating were confirmed by the transmission and scanning electron microscopies.

引用

页码：6869 / 6872

页数：4

共 8 条

[1] THE GYROID - A NEW EQUILIBRIUM MORPHOLOGY IN WEAKLY SEGREGATED DIBLOCK COPOLYMERS
HAJDUK, DA
HARPER, PE
GRUNER, SM
HONEKER, CC
KIM, G
THOMAS, EL
FETTERS, LJ
[J]. MACROMOLECULES, 1994, 27 (15) : 4063 - 4075
[2] BICONTINUOUS MICRODOMAIN MORPHOLOGY OF BLOCK COPOLYMERS .1. TETRAPOD-NETWORK STRUCTURE OF POLYSTYRENE POLYISOPRENE DIBLOCK POLYMERS
HASEGAWA, H
TANAKA, H
YAMASAKI, K
HASHIMOTO, T
[J]. MACROMOLECULES, 1987, 20 (07) : 1651 - 1662
[3] HASHIMOTO T, 1983, BLOCK COPOLYMERS SCI, P63
[4] LEE JS, 1988, MACROMOLECULES, V21, P276
[5] NISHIKAWA Y, UNPUT
[6] SADRON C, 1973, MAKROMOL CHEM, V164, P301
[7] ORDERED BICONTINUOUS DOUBLE-DIAMOND STRUCTURE OF STAR BLOCK COPOLYMERS - A NEW EQUILIBRIUM MICRODOMAIN MORPHOLOGY
THOMAS, EL
ALWARD, DB
KINNING, DJ
MARTIN, DC
HANDLIN, DL
FETTERS, LJ
[J]. MACROMOLECULES, 1986, 19 (08) : 2197 - 2202
[8] Tsutsumi K., UNPUB

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