Two alternative routes for the migratory insertion of a carbene ligand into a C-H bond

被引：20

作者：

Herber, U ^{[1
]}

Bleuel, E ^{[1
]}

Gevert, O ^{[1
]}

Laubender, M ^{[1
]}

Werner, H ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 01期

关键词：

D O I：

10.1021/om970784y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [(eta(5)-C5H5)Rh(=CPh2)(PiPr(3))] (2) with either PF3 or HX (X = CI, CF3CO2) leads to a migratory insertion of the carbene ligand into one of the C-H bonds of the cyclopentadienyl ring. The X-ray crystal structures of [(eta(5)-C5H4CHPh2)Rh(PF3)(PiPr(3))] (5) and [(eta(5)-C5H4CHPh2)RhCl2(PiPr(3))] (7a) have been determined.

引用

页码：10 / 12

页数：3

共 19 条

[1] ASSOCIATIVE SUBSTITUTION-REACTIONS OF METAL-CARBONYLS
BASOLO, F
[J]. INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 100 (01): : 33 - 39
[2] AMPHIPHILIC CARBENE COMPLEXES - BOTH ELECTROPHILES AND NUCLEOPHILES ATTACK THE CARBENE CARBON OF C5H5(CO)2RE=CHR
CASEY, CP
VOSEJPKA, PC
ASKHAM, FR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (09) : 3713 - 3715
[3] Dotz K.H., 1983, TRANSITION METAL CAR
[4] Dotz K.H., 1984, ANGEW CHEM, V96, P573
[5] CARBENE COMPLEXES IN ORGANIC-SYNTHESIS
DOTZ, KH
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (08): : 587 - 608
[6] METALLOCENE CARBENE COMPLEXES AND RELATED-COMPOUNDS OF TITANIUM, ZIRCONIUM, AND HAFNIUM
ERKER, G
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1989, 28 (04) : 397 - 412
[7] ERKER G, 1989, ANGEW CHEM, V101, P411
[8] RECENT ADVANCES IN THE CHEMISTRY OF D(0) ALKYLIDENE AND METALLACYCLOBUTANE COMPLEXES
FELDMAN, J
SCHROCK, RR
[J]. PROGRESS IN INORGANIC CHEMISTRY, 1991, 39 : 1 - 74
[9] POLYMER SYNTHESIS AND ORGANOTRANSITION METAL CHEMISTRY
GRUBBS, RH
TUMAS, W
[J]. SCIENCE, 1989, 243 (4893) : 907 - 915
[10] INTRAMOLECULAR ADDITION-REACTIONS OF FUNCTIONALIZED ARYLCARBENES TO ARENES
GUTH, M
KIRMSE, W
[J]. ACTA CHEMICA SCANDINAVICA, 1992, 46 (07): : 606 - 613

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