Two alternative routes for the migratory insertion of a carbene ligand into a C-H bond

被引:20
作者
Herber, U [1 ]
Bleuel, E [1 ]
Gevert, O [1 ]
Laubender, M [1 ]
Werner, H [1 ]
机构
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
关键词
D O I
10.1021/om970784y
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of [(eta(5)-C5H5)Rh(=CPh2)(PiPr(3))] (2) with either PF3 or HX (X = CI, CF3CO2) leads to a migratory insertion of the carbene ligand into one of the C-H bonds of the cyclopentadienyl ring. The X-ray crystal structures of [(eta(5)-C5H4CHPh2)Rh(PF3)(PiPr(3))] (5) and [(eta(5)-C5H4CHPh2)RhCl2(PiPr(3))] (7a) have been determined.
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页码:10 / 12
页数:3
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