Mixed silicon-graphite composites as anode material for lithium ion batteries influence of preparation conditions on the properties of the material

被引：179

作者：

Dimov, N ^{[1
]}

Kugino, S ^{[1
]}

Yoshio, A ^{[1
]}

机构：

[1] Saga Univ, Dept Appl Chem, Saga 8408502, Japan

来源：

JOURNAL OF POWER SOURCES | 2004年 / 136卷 / 01期

关键词：

silicon; lithium-ion; batteries; anode; composite;

D O I：

10.1016/j.jpowsour.2004.05.012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mixed silicon-graphite composites were studied as an anode material for LIB. Estimation of the capacity of the composite as a function of silicon mass fraction as well as the lithium mole fraction in the final Li-Si alloy was performed. Based on this estimation, appropriate cycling test was introduced. Possible cycling stability region in terms of Si mass fraction, mole fraction of Li in the Li-Si alloy and average particle size was evaluated. (C) 2004 Published by Elsevier B.V.

引用

页码：108 / 114

页数：7

共 12 条

[1] Key factors controlling the reversibility of the reaction of lithium with SnO2 and Sn2BPO6 glass
Courtney, IA
Dahn, JR
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (09) : 2943 - 2948
[2] Carbon-coated silicon as anode material for lithium ion batteries: advantages and limitations
Dimov, N
Kugino, S
Yoshio, M
[J]. ELECTROCHIMICA ACTA, 2003, 48 (11) : 1579 - 1587
[3] Characterization of carbon-coated silicon - Structural evolution and possible limitations
Dimov, N
Fukuda, K
Umeno, T
Kugino, S
Yoshio, M
[J]. JOURNAL OF POWER SOURCES, 2003, 114 (01) : 88 - 95
[4] Decrepitation Model For Capacity Loss During Cycling of Alloys in Rechargeable Electrochemical Systems
Huggins, R. A.
Nix, W. D.
[J]. IONICS, 2000, 6 (1-2) : 57 - 63
[5] Tin-based amorphous oxide: A high-capacity lithium-ion-storage material
Idota, Y
Kubota, T
Matsufuji, A
Maekawa, Y
Miyasaka, T
[J]. SCIENCE, 1997, 276 (5317) : 1395 - 1397
[6] Amorphous silicon thin-film negative electrode prepared by low pressure chemical vapor deposition for lithium-ion batteries
Jung, HJ
Park, M
Han, SH
Lim, H
Joo, SK
[J]. SOLID STATE COMMUNICATIONS, 2003, 125 (7-8) : 387 - 390
[7] Kim I, 2000, ELECTROCHEM SOLID ST, V3, P493
[8] The crystal structural evolution of nano-Si anode caused by lithium insertion and extraction at room temperature
Li, H
Huang, XJ
Chen, LQ
Zhou, GW
Zhang, Z
Yu, DP
Mo, YJ
Pei, N
[J]. SOLID STATE IONICS, 2000, 135 (1-4) : 181 - 191
[9] Umeno T, 2001, CHEM LETT, P1186
[10] Sub-microcrystalline Sn and Sn-SnSb powders as lithium storage materials for lithium-ion batteries
Yang, J
Wachtler, M
Winter, M
Besenhard, JO
[J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 1999, 2 (04) : 161 - 163

← 1 2 →