The first structurally characterized aluminum compound with two SH groups:: [LAI(SH)2] (L=N(Ar)C(Me)CHC(Me)N(Ar), Ar=2,6-i-Pr2C6H3) and the catalytic properties of the sulfur P(NMe2)3 system

被引：64

作者：

Jancik, V ^{[1
]}

Peng, Y ^{[1
]}

Roesky, HW ^{[1
]}

Li, JY ^{[1
]}

Neculai, D ^{[1
]}

Neculai, AM ^{[1
]}

Herbst-Irmer, R ^{[1
]}

机构：

[1] Univ Gottingen, Inst Inorgan Chem, D-37077 Gottingen, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 06期

关键词：

D O I：

10.1021/ja028801k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Surprisingly stable is the bis(hydrogen sulfide) of aluminum LAl(SH)2 with two terminal arranged SH groups. The insertion of sulfur into the Al-H bonds is catalyzed by SP(NMe2)3. A possible mechanism is discussed. Copyright © 2003 American Chemical Society.

引用

页码：1452 / 1453

页数：2

共 33 条

[1] INFRARED SPECTRUM OF HYDROGEN SULFIDE [J].

ALLEN, HC ;

PLYLER, EK .

JOURNAL OF CHEMICAL PHYSICS, 1956, 25 (06) :1132-1136

[2] INFRARED SPECTRUM OF HYDROGEN SULFIDE FROM 2200-2800-CM-1 [J].

ALLEN, HC ;

BLAINE, LR ;

PLYER, EK .

JOURNAL OF CHEMICAL PHYSICS, 1956, 24 (01) :35-38

[3]

[Anonymous], 1983, INORGANIC CHEM PRINC

[4] MONONUCLEAR COMPLEXES OF CR(II) AND FE(II) WITH TERMINAL SH-GROUPS - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF TRANS-M(SH)2(DMPE)2 (M = CR, FE - DMPE = 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE) [J].

ARIF, AM ;

HEFNER, JG ;

JONES, RA ;

KOSCHMIEDER, SU .

JOURNAL OF COORDINATION CHEMISTRY, 1991, 23 (1-4) :13-19

[5] MOCVD OF GROUP-III CHALCOGENIDES [J].

BARREN, AR .

ADVANCED MATERIALS FOR OPTICS AND ELECTRONICS, 1995, 5 (05) :245-258

[6] REACTIONS OF BIS(CYCLOPENTADIENYL)TITANIUM AND BIS(PENTAMETHYLCYCLOPENTADIENYL)TITANIUM AND BIS(CYCLOPENTADIENYL)TITANIUM AND BIS(PENTAMETHYLCYCLOPENTADIENYL)ZIRCONIUM DICARBONYLS WITH WATER AND DIHYDROGEN SULFIDE - EVOLUTION OF DIHYDROGEN AND FORMATION OF OXO OR SULFIDO MONOMERS, DIMERS, OR CLUSTERS [J].

BOTTOMLEY, F ;

DRUMMOND, DF ;

EGHAREVBA, GO ;

WHITE, PS .

ORGANOMETALLICS, 1986, 5 (08) :1620-1625

[7] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF CIS-PT(SH)2(PPH3)2 AND RELATED ALKYL AND ARYL THIOLATO COMPLEXES [J].

BRIANT, CE ;

HUGHES, GR ;

MINSHALL, PC ;

MINGOS, DMP .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 202 (01) :C18-C20

[8]

BRISSE F, 1983, NOUV J CHIM, V7, P391

[9]

Cui C, 2000, ANGEW CHEM INT EDIT, V39, P1815, DOI 10.1002/(SICI)1521-3773(20000515)39:10<1815::AID-ANIE1815>3.0.CO

[10]

2-W

← 1 2 3 4 →