Proof of the presence of racemic forms of arylglycerol-β-aryl ether structure in lignin:: studies on the stereo structure of lignin by ozonation

被引：38

作者：

Akiyama, T

Magara, K

Matsumoto, Y

Meshitsuka, G

Ishizu, A

Lundquist, K

机构：

[1] Univ Tokyo, Grad Sch Agr & Life Sci, Wood Chem Lab, Bunkyo Ku, Tokyo 1138657, Japan

[2] Forestry & Forest Prod Res Inst, Tsukuba, Ibaraki 3058687, Japan

[3] Nihon Univ, Coll Agr & Vet Med, Fujisawa, Kanagawa 2528510, Japan

[4] Chalmers Univ Technol, S-41296 Gothenburg, Sweden

来源：

JOURNAL OF WOOD SCIENCE | 2000年 / 46卷 / 05期

关键词：

ozonation; arylglycerol-beta-aryl ether structure; erythro and threo; stereo structure; lignin;

D O I：

10.1007/BF00776407

中图分类号：

S7 [林业];

学科分类号：

0829 ; 0907 ;

摘要：

Recent rapid progress of the biosynthetic study of lignan, especially finding a new type of protein that regulates the stereo structure of lignan,(1) seems to "re-create" an interest in the investigation of optical activity of lignin, although lignin has long been assumed to be optically inactive.

引用

页码：414 / 415

页数：2

共 4 条

[1] Stereoselective bimolecular phenoxy radical coupling by an auxiliary (dirigent) protein without an active center
Davin, LB
Wang, HB
Crowell, AL
Bedgar, DL
Martin, DM
Sarkanen, S
Lewis, NG
[J]. SCIENCE, 1997, 275 (5298) : 362 - 366
[2] MATSUMOTO Y, 1993, MOKUZAI GAKKAISHI, V39, P734
[3] MATSUMOTO Y, 1986, HOLZFORSCHUNG, V40, P81
[4] Are lignins optically active?
Ralph, J
Peng, JP
Lu, FC
Hatfield, RD
Helm, RF
[J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1999, 47 (08) : 2991 - 2996

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