Self-assembly of interpenetrating coordination nets formed from interpenetrating cationic and anionic three-dimentsional diamondoid cluster coordination polymers

被引：184

作者：

Liang, K ^{[1
]}

Zheng, HG

Song, YL

Lappert, ME

Li, YZ

Xin, XQ

Huang, ZX

Chen, JT

Lu, SF

机构：

[1] Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Harbin Inst Technol, Dept Appl Phys, Harbin 150001, Peoples R China

[3] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England

[4] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 43期

关键词：

clusters; coordination polymers; heterometallic complexes; nonlinear optics; organic-inorganic hybrid composites;

D O I：

10.1002/anie.200460681

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetrathiometalates [WS4]2- are the nodal building blocks in a new kind of heterometallic interpenetrating three-dimensional cluster coordination polymer (see picture) that has interesting nonlinear optical properties. The polymer exhibits optical self-focusing behavior and reverse saturable absorption effects.

引用

页码：5776 / 5779

页数：4

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