Toward controlled spacing in one-dimensional molecular chains: Alkyl-chain-functionalized fullerenes in carbon nanotubes

被引：39

作者：

Chamberlain, Thomas W.

Camenisch, Andrew

Champness, Neil R.

Briggs, G. Andrew D.

Benjamin, Simon C.

Ardavan, Arzhang

Khlobystov, Andrei N. ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[2] Univ Oxford, Dept Mat, Oxford OX1 3PH, England

[3] Univ Oxford, Dept Phys, Oxford OX1 3PU, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 27期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1021/ja071803q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A range of fullerenes (C-60) functionalized with long alkyl chains have been synthesized and inserted into single-walled carbon nanotubes. The impact of the alkyl chain length and of the type of linker between the addend and the fullerene cage on the geometry of molecular arrays in nanotube has been studied by high-resolution transmission electron microscopy. In the presence of functional groups the mean interfullerene separations are significantly increased by 2-8 nm depending on the length of the alkyl chain, but the periodicity of the fullerene arrays is disrupted due to the conformational flexibility of the alkyl groups.

引用

页码：8609 / 8614

页数：6

共 32 条

[1] Sequence-specific modification of guanosine in DNA by a C-60-linked deoxyoligonucleotide: Evidence for a non-singlet oxygen mechanism
An, YZ
Chen, CHB
Anderson, JL
Sigman, DS
Foote, CS
Rubin, Y
[J]. TETRAHEDRON, 1996, 52 (14) : 5179 - 5189
[2] Adsorption modification of single-walled carbon nanotubes with tetraazaannulene macrocyclic complexes
Basiuk, EV
Rybak-Akimova, EV
Basiuk, VA
Acosta-Najarro, D
Saniger, JM
[J]. NANO LETTERS, 2002, 2 (11) : 1249 - 1252
[3] Towards a fullerene-based quantum computer
Benjamin, Simon C.
Ardavan, Arzhang
Briggs, G. Andrew D.
Britz, David A.
Gunlycke, Daniel
Jefferson, John
Jones, Mark A. G.
Leigh, David F.
Lovett, Brendon W.
Khlobystov, Andrei N.
Lyon, S. A.
Morton, John J. L.
Porfyrakis, Kyriakos
Sambrook, Mark R.
Tyryshkin, Alexei M.
[J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 2006, 18 (21) : S867 - S883
[4] Chemical reactions inside single-walled carbon nano test-tubes
Britz, DA
Khlobystov, AN
Porfyrakis, K
Ardavan, A
Briggs, GAD
[J]. CHEMICAL COMMUNICATIONS, 2005, (01) : 37 - 39
[5] Noncovalent interactions of molecules with single walled carbon nanotubes
Britz, David A.
Khlobystov, Andrei N.
[J]. CHEMICAL SOCIETY REVIEWS, 2006, 35 (07) : 637 - 659
[6] Encapsulation of RexOy clusters within single-walled carbon nanotubes and their in tubulo reduction and sintering to Re metal
Costa, PMFJ
Sloan, J
Rutherford, T
Green, MLH
[J]. CHEMISTRY OF MATERIALS, 2005, 17 (26) : 6579 - 6582
[7] Carbon nanotube inner phase chemistry:: The Cl- exchange SN2 reaction
Halls, MD
Raghavachari, K
[J]. NANO LETTERS, 2005, 5 (10) : 1861 - 1866
[8] Halls MD, 2002, J PHYS CHEM B, V106, P1921, DOI 10.1021/jp0l37165
[9] Electron diffraction study of one-dimensional crystals of fullerenes
Hirahara, K
Bandow, S
Suenaga, K
Kato, H
Okazaki, T
Shinohara, H
Iijima, S
[J]. PHYSICAL REVIEW B, 2001, 64 (11)
[10] Mapping the one-dimensional electronic states of nanotube peapod structures
Hornbaker, DJ
Kahng, SJ
Misra, S
Smith, BW
Johnson, AT
Mele, EJ
Luzzi, DE
Yazdani, A
[J]. SCIENCE, 2002, 295 (5556) : 828 - 831

← 1 2 3 4 →