Ozone loss rates in the Arctic stratosphere in the winter 1994/1995:: Model simulations underestimate results of the Match analysis

被引:37
作者
Becker, G
Müller, R
McKenna, DS
Rex, M
Carslaw, KS
Oelhaf, H
机构
[1] Forschungszentrum Julich, Inst Stratosphar Chem IGC 1, D-52425 Julich, Germany
[2] Forschungszentrum Karlsruhe, Inst Meteorol & Klimaforsch, D-76021 Karlsruhe, Germany
[3] CALTECH, Jet Prop Lab, Pasadena, CA USA
[4] Max Planck Inst Chem, Mainz, Germany
关键词
D O I
10.1029/2000JD900056
中图分类号
P4 [大气科学(气象学)];
学科分类号
0706 ; 070601 ;
摘要
We present box model simulations of ozone loss rates in the Arctic lower stratosphere for the winter 1994/1995, The ozone loss was simulated along each of the trajectories of the Match data set for 1994/1995 to conduct a quantitative comparison with the Match results, The simulated ozone loss rates reach their maximum value of approximate to 4 ppb per sunlit hour at the end of January, For this period and for potential temperatures below 475 K the model results are in good agreement with the Match results, but for potential temperatures above 475 K the model underestimates the ozone loss rate by up to a factor of 2. This difference cannot be explained by known uncertainties of the model. Enhanced ozone loss has also been observed in March 1995 for potential temperatures below 475 K. These loss rates are also substantially underestimated by the model, but are within the range of the model uncertainties, In particular, the ozone loss rates simulated for March 1995 strongly depend on the extent of denitrification.
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收藏
页码:15175 / 15184
页数:10
相关论文
共 49 条
[1]   Spring ozone column values over Thule, Greenland in the period 1991-1998 [J].
Andersen, SB .
GEOPHYSICAL RESEARCH LETTERS, 1999, 26 (02) :193-196
[2]   FREE-RADICALS WITHIN THE ANTARCTIC VORTEX - THE ROLE OF CFCS IN ANTARCTIC OZONE LOSS [J].
ANDERSON, JG ;
TOOHEY, DW ;
BRUNE, WH .
SCIENCE, 1991, 251 (4989) :39-46
[3]   Observations of nitric acid perturbations in the winter Arctic stratosphere: Evidence for PSC sedimentation [J].
Arnold, F ;
Burger, V ;
Gollinger, K ;
Roncossek, M ;
Schneider, J ;
Spreng, S .
JOURNAL OF ATMOSPHERIC CHEMISTRY, 1998, 30 (01) :49-59
[4]   Ozone loss rates in the Arctic stratosphere in the winter 1991/92: Model calculations compared with Match results [J].
Becker, G ;
Muller, R ;
McKenna, DS ;
Rex, M ;
Carslaw, KS .
GEOPHYSICAL RESEARCH LETTERS, 1998, 25 (23) :4325-4328
[5]  
BECKER G, 2000, IN PRESS J ATMOS CHE
[6]   OZONE AND AEROSOL CHANGES DURING THE 1991-1992 AIRBORNE ARCTIC STRATOSPHERIC EXPEDITION [J].
BROWELL, EV ;
BUTLER, CF ;
FENN, MA ;
GRANT, WB ;
ISMAIL, S ;
SCHOEBERL, MR ;
TOON, OB ;
LOEWENSTEIN, M ;
PODOLSKE, JR .
SCIENCE, 1993, 261 (5125) :1155-1158
[7]   Uncertainties in reactive uptake coefficients for solid stratospheric particles .2. Effect on ozone depletion [J].
Carslaw, KS ;
Peter, T ;
Muller, R .
GEOPHYSICAL RESEARCH LETTERS, 1997, 24 (14) :1747-1750
[8]   AN ANALYTIC-EXPRESSION FOR THE COMPOSITION OF AQUEOUS HNO3-H2SO4 STRATOSPHERIC AEROSOLS INCLUDING GAS-PHASE REMOVAL OF HNO3 [J].
CARSLAW, KS ;
LUO, BP ;
PETER, T .
GEOPHYSICAL RESEARCH LETTERS, 1995, 22 (14) :1877-1880
[9]  
DeMore W.B., 1997, JPL PUBL, P97
[10]   Arctic chemical ozone depletion during the 1994-1995 winter deduced from POAM II satellite observations and the REPROBUS three-dimensional model [J].
Deniel, C ;
Bevilacqua, RM ;
Pommereau, JP ;
Lefevre, F .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1998, 103 (D15) :19231-19244