Selective formation of 2-hydroxy-3,3-bis(hydroxymethyl)-gamma-butyrolactone from formaldehyde on hydrotalcite-type catalysts

被引：5

作者：

Mizutani, T ^{[1
]}

Miki, Y ^{[1
]}

Nakashima, R ^{[1
]}

Fujita, H ^{[1
]}

Ogoshi, H ^{[1
]}

机构：

[1] TOTTORI UNIV, FAC ENGN, DEPT MAT SCI, TOTTORI 680, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1996年 / 69卷 / 02期

关键词：

D O I：

10.1246/bcsj.69.425

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As a model for prebiotic sugar formation under neutral to acidic conditions, reactions of formaldehyde over hydrotalcite-type catalysts were investigated. Heating an aqueous solution of formaldehyde at 140-200 degrees C for 12 h over Ni-Fe hydrotalcite-type catalyst afforded 2-hydroxy-3,3-bis(hydroxymethyl)-gamma-butyrolactone selectively, a 5.8% yield based on gas-liquid chromatographic analysis. The structure was identified by H-1 and (13)CNMR and H-1-C-13 HSQC, HMBC and C-13-C-13 2D INADEQUATE NMR experiments.

引用

页码：425 / 429

页数：5

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