Modeling of thermo-physical processes in liquid ceramic precursor droplets injected into a plasma jet

被引:39
作者
Basu, Saptarshi [1 ]
Cetegen, Baki M. [1 ]
机构
[1] Univ Connecticut, Dept Mech Engn, Storrs, CT 06269 USA
关键词
droplet/plasma interaction; solute precipitation; droplet heating; vaporization; ceramic precursors;
D O I
10.1016/j.ijheatmasstransfer.2007.01.036
中图分类号
O414.1 [热力学];
学科分类号
摘要
Modeling of liquid ceramic precursor droplets axially injected into a plasma is presented. Droplets undergo heating and solvent vaporization leading to high solute concentration near droplet surface. At a critical solute super-saturation concentration, precipitation is postulated to occur forming a precipitate shell around liquid core. Internal pressurization and rupture of shell occur subsequently. Droplet size, shell porosity and thickness effects were studied. Timescales of internal pressurization and precipitate formation are of the order of microsecond and millisecond, respectively. Small droplets (d <= 5 mu m) tend to form thick shells and are less likely to undergo shell fracture compared to larger droplets. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3278 / 3290
页数:13
相关论文
共 26 条
[1]   Mechanisms of ceramic coating deposition in solution-precursor plasma spray [J].
Bhatia, T ;
Ozturk, A ;
Xie, LD ;
Jordan, EH ;
Cetegen, BM ;
Gell, M ;
Ma, XQ ;
Padture, NP .
JOURNAL OF MATERIALS RESEARCH, 2002, 17 (09) :2363-2372
[2]   Particle structure control through intraparticle reactions by spray pyrolysis [J].
Che, S ;
Sakurai, O ;
Shinozaki, K ;
Mizutani, N .
JOURNAL OF AEROSOL SCIENCE, 1998, 29 (03) :271-278
[3]   STUDIES OF CONCENTRATED ELECTROLYTE-SOLUTIONS USING THE ELECTRODYNAMIC BALANCE .3. SOLUTE NUCLEATION [J].
COHEN, MD ;
FLAGAN, RC ;
SEINFELD, JH .
JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (17) :4583-4590
[4]  
FUCHS NA, 1959, EVAPORATION DROPLET
[5]   Highly durable thermal barrier coatings made by the solution precursor plasma spray process [J].
Gell, M ;
Xie, LD ;
Ma, XQ ;
Jordan, EH ;
Padture, NP .
SURFACE & COATINGS TECHNOLOGY, 2004, 177 :97-102
[6]   Morphology of single-component particles produced by spray pyrolysis [J].
Jain, S ;
Skamser, DJ ;
Kodas, TT .
AEROSOL SCIENCE AND TECHNOLOGY, 1997, 27 (05) :575-590
[7]   MODELING OF SOLID PARTICLE FORMATION DURING SOLUTION AEROSOL THERMOLYSIS - THE EVAPORATION STAGE [J].
JAYANTHI, GV ;
ZHANG, SC ;
MESSING, GL .
AEROSOL SCIENCE AND TECHNOLOGY, 1993, 19 (04) :478-490
[8]   Superior thermal barrier coatings using solution precursor plasma spray [J].
Jordan, EH ;
Xie, L ;
Ma, X ;
Gell, M ;
Padture, NP ;
Cetegen, B ;
Ozturk, A ;
Roth, J ;
Xiao, TD ;
Bryant, PEC .
JOURNAL OF THERMAL SPRAY TECHNOLOGY, 2004, 13 (01) :57-65
[9]  
Kozeny J., 1927, Proc. Natl. Acad. Sci. USA, V136, P271
[10]   MORPHOLOGICAL CONTROL OF PARTICLES GENERATED FROM THE EVAPORATION OF SOLUTION DROPLETS - THEORETICAL CONSIDERATIONS [J].
LEONG, KH .
JOURNAL OF AEROSOL SCIENCE, 1987, 18 (05) :511-524