A highly symmetric porous framework with multi-intersecting open channels

被引：75

作者：

Lin, Zheng-Zhong

Jiang, Fei-Long

Chen, Lian

Yue, Cheng-Yang

Yuan, Da-Qiang

Lan, An-Jian

Hong, Mao-Chun ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Fuzhou, Peoples R China

[2] Jimei Univ, Coll Biol Engn, Xiamen 361021, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2007年 / 7卷 / 09期

关键词：

D O I：

10.1021/cg060732o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A porous anionic framework with cubic symmetry and multi-intersecting open channels, {[H(2)tmdp](3)[In-6(btc)(8)]center dot 40H(2)O}(n) (1) (tmdp= 4,4'-trimethylene dipiperidine, H(3)btc=1,3,5-benzenetricarboxylic acid), is reported. Complex 1 crystallizes in the cubic space group I (4) over bar 3d (a = b = c = 20.3732(g) angstrom, V = 8456.2(6) angstrom(3), and Z = 2). Its cagelike units, Ing(btc)(11), constitute a large accessible void with 65.4% of the total volume. The cationic guests located in the channels can be exchanged with inorganic ions, such as K+, NH4+, Ca2+, Sr2+, and Ba2+.

引用

页码：1712 / 1715

页数：4

共 61 条

[1] New tricks for an old dog:: The carbonate ion as a building block for networks including examples of composition [Cu6(CO3)12-{C(NH2)3}8]4- with the sodalite topology
Abrahams, BF
Haywood, MG
Robson, R
Slizys, DA
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (10) : 1112 - 1115
[2] Templated assembly of sulfide nanoclusters into Cubic-C3N4 type framework
Bu, XH
Zheng, NF
Li, YQ
Feng, PY
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (20) : 6024 - 6025
[3] A novel layered indium sulfide material consisting of corner and edge shared InS4 tetrahedra:: synthesis and structural characterization Of DPA-InS-SB3
Cahill, CL
Gugliotta, B
Parise, JB
[J]. CHEMICAL COMMUNICATIONS, 1998, (16) : 1715 - 1716
[4] Design of frameworks with mixed triangular and octahedral building blocks exemplified by the structure of [Zn4O(TCA)2] having the pyrite topology
Chae, HK
Kim, J
Friedrichs, OD
O'Keefe, M
Yaghi, OM
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (33) : 3907 - 3909
[5] Interwoven metal-organic framework on a periodic minimal surface with extra-large pores
Chen, BL
Eddaoudi, M
Hyde, ST
O'Keeffe, M
Yaghi, OM
[J]. SCIENCE, 2001, 291 (5506) : 1021 - 1023
[6] Hydrothermal synthesis of two layered indium oxalates with 12-membered apertures
Chen, ZX
Zhou, YM
Weng, LH
Zhang, HY
Zhao, DY
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 2003, 173 (02) : 435 - 441
[7] Structural variability of cobalt(II) coordination polymers:: Three polymorphs of Co3(TMA)2 [TAU = trimesate, C6H3(COO)33-]
Cheng, DP
Khan, MA
Houser, RP
[J]. CRYSTAL GROWTH & DESIGN, 2004, 4 (03) : 599 - 604
[8] Choi HJ, 1999, ANGEW CHEM INT EDIT, V38, P1405, DOI 10.1002/(SICI)1521-3773(19990517)38:10<1405::AID-ANIE1405>3.0.CO
[9] 2-H
[10] Self-assembly of molecular brick wall and molecular honeycomb from nickel(II) macrocycle and 1,3,5-benzenetricarboxylate: Guest-dependent host structures
Choi, HJ
Suh, MP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (41) : 10622 - 10628

← 1 2 3 4 5 6 7 →