Dendritic rods with a poly(triacetylene) backbone: insulated molecular wires

被引:68
作者
Schenning, APHJ
Martin, RE
Ito, M
Diederich, F
Boudon, C
Gisselbrecht, JP
Gross, M
机构
[1] ETH Zentrum, Organ Chem Lab, CH-8092 Zurich, Switzerland
[2] Univ Louis Pasteur Strasbourg 1, Fac Chim, CNRS, URA 405,Lab Electrochim & Chim Phys Corps Solide, F-67008 Strasbourg, France
关键词
D O I
10.1039/a801269e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Multinanometer long phenylacetylene-end-capped poly(triacetylene) (PTA) oligomers with dendritic side chains of generation one to three have been prepared; UV-VIS measurements indicate that there is no loss of pi-electron conjugation along the PTA backbone in the higher generation compounds despite distortion from planarity due to the bulky dendritic wedges.
引用
收藏
页码:1013 / 1014
页数:2
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