The silicomolybdic acid spectrophotometric method and its application to silicate/biopolymer interaction studies

被引:110
作者
Coradin, T
Eglin, D
Livage, J
机构
[1] Univ Paris 06, Lab Chim Mat Condensee, CNRS, UMR 7574, F-75252 Paris 05, France
[2] Coll France, F-75005 Paris, France
来源
SPECTROSCOPY-AN INTERNATIONAL JOURNAL | 2004年 / 18卷 / 04期
关键词
D O I
10.1155/2004/356207
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
The possibility to understand natural strategies to build-up silica SiO2 networks relies on the investigations of the kinetics of silica precursors polymerization in the presence of biopolymers. The silicomolybdic acid spectrophotometric method allows to study this process at the molecular level, provided that reliable procedures are available. Moreover, special care must be taken to avoid interfering processes induced by the inorganic and/or bio-organic species found in solution. In order to illustrate the possibilities and limitations of this method, different sets of data are presented and discussed in the context of silica formation control by natural systems.
引用
收藏
页码:567 / 576
页数:10
相关论文
共 48 条
[1]   Patterned crystallization of calcite in vivo and in vitro [J].
Aizenberg, J .
JOURNAL OF CRYSTAL GROWTH, 2000, 211 (1-4) :143-148
[2]   THE REACTION OF LOW MOLECULAR WEIGHT SILICIC ACIDS WITH MOLYBDIC ACID [J].
ALEXANDER, GB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (22) :5655-5657
[3]  
[Anonymous], 1942, IND ENG CHEM ANAL ED, DOI [DOI 10.1021/I560111A027, 10.1021/i560111a027]
[4]   FLOW-INJECTION ANALYSIS FOR POWER-PLANTS - EVALUATION OF DETECTORS FOR THE DETERMINATION OF CONTROL PARAMETERS IN CONDITIONED WATER STEAM CYCLES [J].
BALCONI, ML ;
SIGON, F ;
BORGARELLO, M ;
FERRAROLI, R ;
REALINI, F .
ANALYTICA CHIMICA ACTA, 1990, 234 (01) :167-173
[5]  
Brinker C.J., 1990, PHYS CHEM SOL GEL PR
[6]  
Coradin T, 2002, MATER RES SOC SYMP P, V724, P147
[7]   Interactions of bovine serum albumin and lysozyme with sodium silicate solutions [J].
Coradin, T ;
Coupé, A ;
Livage, J .
COLLOIDS AND SURFACES B-BIOINTERFACES, 2003, 29 (2-3) :189-196
[8]   Biogenic silica patterning: Simple chemistry or subtle biology? [J].
Coradin, T ;
Lopez, PJ .
CHEMBIOCHEM, 2003, 4 (04) :251-259
[9]   Interactions of amino-containing peptides with sodium silicate and colloidal silica: A biomimetic approach of silicification [J].
Coradin, T ;
Durupthy, O ;
Livage, J .
LANGMUIR, 2002, 18 (06) :2331-2336
[10]   Effect of some amino acids and peptides on silicic acid polymerization [J].
Coradin, T ;
Livage, J .
COLLOIDS AND SURFACES B-BIOINTERFACES, 2001, 21 (04) :329-336