Design of molecular materials combining magnetic, electrical and optical properties

被引:106
作者
Coronado, E [1 ]
Clemente-León, M [1 ]
Galán-Mascarós, JR [1 ]
Giménez-Saiz, C [1 ]
Gómez-García, CJ [1 ]
Martínez-Ferrero, E [1 ]
机构
[1] Univ Valencia, Dept Quim Inorgan, E-46100 Burjassot, Spain
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 21期
关键词
D O I
10.1039/b003396k
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The possibilities offered by hybrid functional materials formed by two molecular networks in the context of crystal engineering are illustrated with two different examples: (i) hybrid magnets constructed from combination of an extended ferromagnetic or ferrimagnetic inorganic network, with a molecular paramagnetic metal complex acting as template. (ii) Hybrid organic-inorganic compounds combining an organic pi -electron donor network that furnishes the pathway for electronic conductivity, with inorganic metal complexes that act as structural and/or magnetic components. These examples illustrate how this hybrid approach allows the design of molecular materials combining non-conventional magnetic, electrical and optical properties.
引用
收藏
页码:3955 / 3961
页数:7
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