Light metal hydrides and complex hydrides for hydrogen storage

被引：608

作者：

Schüth, F ^{[1
]}

Bogdanovic, B ^{[1
]}

Felderhoff, M ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 20期

关键词：

D O I：

10.1039/b406522k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The availability of feasible methods for hydrogen storage is one of the key-maybe the key-requirements for the large scale application of PEM fuel cells in cars. There are in principle four different approaches, i.e. cryostorage in liquid form, high pressure storage, storage in the form of a chemical compound which is converted to hydrogen by on-board reforming, or reversible chemical storage in different kinds of storage materials. New developments in the field of chemical storage make such systems attractive compared to the other options. This review will discuss the different possibilities for chemical storage of hydrogen and the focus on the presently most advanced system with respect to storage capacity and kinetics, i.e. catalyzed alanates, especially NaAlH4.

引用

页码：2249 / 2258

页数：10

共 80 条

[1]

Amendola S.C., 2003, System for hydrogen generation, Patent No. [US 6534033 B1, 6534033]

[2] Hydrogen desorption kinetics in transition metal modified NaAlH4 [J].

Anton, DL .

JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 356 :400-404

[3] Rapid solid-state transformation of tetrahedral [AlH4]- into octahedral [AlH6]3- in lithium aluminohydride [J].

Balema, VP ;

Dennis, KW ;

Pecharsky, VK .

CHEMICAL COMMUNICATIONS, 2000, (17) :1665-1666

[4] Solid state phase transformations in LiAlH4 during high-energy ball-milling [J].

Balema, VP ;

Pecharsky, VK ;

Dennis, KW .

JOURNAL OF ALLOYS AND COMPOUNDS, 2000, 313 (1-2) :69-74

[5] Titanium catalyzed solid-state transformations in LiAlH4 during high-energy ball-milling [J].

Balema, VP ;

Wiench, JW ;

Dennis, KW ;

Pruski, M ;

Pecharsky, VK .

JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 329 (1-2) :108-114

[6] Recording of hydrogen evolution -: a way for controlling the doping process of sodium alanate by ball milling [J].

Bellosta von Colbe, JM ;

Bogdanovic, B ;

Felderhoff, M ;

Pommerin, A ;

Schüth, F .

JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 370 (1-2) :104-109

[7] Ti-doped NaAlH4 as a hydrogen-storage material -: preparation by Ti-catalyzed hydrogenation of aluminum powder in conjunction with sodium hydride [J].

Bogdanovic, B ;

Schwickardi, M .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2001, 72 (02) :221-223

[8] Ti-doped alkali metal aluminium hydrides as potential novel reversible hydrogen storage materials [J].

Bogdanovic, B ;

Schwickardi, M .

JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 253 (1-2) :1-9

[9] ACTIVE MGH2-MG SYSTEMS FOR REVERSIBLE CHEMICAL ENERGY-STORAGE [J].

BOGDANOVIC, B ;

RITTER, A ;

SPLIETHOFF, B .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (03) :223-234

[10] Thermodynamics and dynamics of the Mg-Fe-H system and its potential for thermochemical thermal energy storage [J].

Bogdanovic, B ;

Reiser, A ;

Schlichte, K ;

Spliethoff, B ;

Tesche, B .

JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 345 (1-2) :77-89

← 1 2 3 4 5 6 7 8 →