Synthesisand characterization of a novel hyperbranched polyether

被引：20

作者：

Borah, J ^{[1
]}

Karak, N ^{[1
]}

机构：

[1] Tezpur Univ, Dept Chem Sci, Tezpur 784028, Assam, India

来源：

POLYMER INTERNATIONAL | 2004年 / 53卷 / 12期

关键词：

nucleophilic displacement polymerization; hyperbranched polymer; polyether; single-step synthesis; cyanuric chloride;

D O I：

10.1002/pi.1622

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A hyperbranched polyether has been synthesized by a single-step nucleophilic displacement polymerization technique between cyanuric chloride and the sodium salt of bisphenol-A. The effects of various reaction parameters on the yield, and molecular weight, as measured by the intrinsic viscosity of the polymer, have been studied. The synthesized polymer has been characterized by FT-IR, UV and H-1 NMR spectroscopies, elemental analysis, solubility and viscosity measurements. The polymer is soluble in highly polar solvents such as N,N-dimethylacetamide, N,N-dimethylformamide and dimethyl sulfoxide, partially soluble in dilute aqueous NaOH solution, methanol, ethanol, chloroform, etc., but insoluble in water and non-polar hydrocarbon solvents. The solubility parameter of the hyperbranched polymer has also been measured experimentally. (C) 2004 Society of Chemical Industry

引用

页码：2026 / 2030

页数：5

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