Saponin induced clouding behavior of triton X-100 and methylcellulose

被引:24
作者
Chatterjee, A
Roy, BK
Moulik, SR [1 ]
Sahu, NP
Mondal, NB
机构
[1] Jadavpur Univ, Dept Chem, Ctr Surface Sci, Kolkata 700032, W Bengal, India
[2] Indian Inst Chem Biol, Kolkata 700032, W Bengal, India
关键词
D O I
10.1081/DIS-120015972
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The clouding behaviors of the surfactant p-tert-octylphenoxypolyoxyethylene ether (TX-100) and the water soluble polymer methylcellulose (MC) have been investigated in presence of two saponins, saponin-I (mixture of acaciaside A, acaciaside B, proacaciaside-I, proacaciaside-II, and acaciamine) and saponin-II (mixture of mimusopin and mimusopsin). The saponins have been observed to significantly prevent the clouding of both TX-100 and MC at low concentrations. Besides presenting the cloud points at different concentrations of the saponins, the energetics of the clouding process in terms of the solubilities of TX-100 and MC have also been determined.
引用
收藏
页码:747 / 757
页数:11
相关论文
共 29 条
[1]  
[Anonymous], 1976, POLYETHYLENE OXIDE
[2]   Effect of hydrotropes on the volume phase transition in poly(N-isopropylacrylamide) hydrogel [J].
Dhara, D ;
Chatterji, PR .
LANGMUIR, 1999, 15 (04) :930-935
[3]   SALT EFFECTS ON THE CLOUD POINT OF THE POLY(ETHYLENE OXIDE) + WATER-SYSTEM [J].
FLORIN, E ;
KJELLANDER, R ;
ERIKSSON, JC .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1984, 80 :2889-2910
[4]  
Flory P.J., 1953, PRINCIPLES POLYM CHE
[5]   Cloud point of mixtures of polypropylene glycol and triton X-100 in aqueous solutions [J].
GaleraGomez, PA ;
Gu, T .
LANGMUIR, 1996, 12 (10) :2602-2604
[6]   Isolation and structure elucidation of three triterpenoid saponins from Acacia auriculiformis [J].
Garai, S ;
Mahato, SB .
PHYTOCHEMISTRY, 1997, 44 (01) :137-140
[7]  
Ghosh S, 1999, INDIAN J CHEM A, V38, P201
[8]  
GUPTA DR, 1990, INDIAN J CHEM B, V29, P268
[9]   LIQUID LIQUID-PHASE SEPARATION IN DILUTE AQUEOUS-SOLUTIONS OF SURFACTANTS - THE EFFECT OF ADDED SALT [J].
IMAE, T ;
SASAKI, M ;
ABE, A ;
IKEDA, S .
LANGMUIR, 1988, 4 (02) :414-418
[10]   PHASE-DIAGRAMS OF NONIONIC POLYMER WATER-SYSTEMS - EXPERIMENTAL AND THEORETICAL-STUDIES OF THE EFFECTS OF SURFACTANTS AND OTHER COSOLUTES [J].
KARLSTROM, G ;
CARLSSON, A ;
LINDMAN, B .
JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (12) :5005-5015