C-H activation of alkanes and arenes catalyzed by an O-donor bis(tropolonato)iridium(III) complex

被引：24

作者：

Bhalla, G ^{[1
]}

Periana, RA ^{[1
]}

机构：

[1] Univ So Calif, Loker Hydrocarbon Res Inst, Dept Chem, Los Angeles, CA 90089 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 10期

关键词：

C-H activation; homogeneous catalysis; iridium; O ligands;

D O I：

10.1002/anie.200462065

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stable and swift: The title complex is stable to air and water under thermal conditions. It efficiently activates the C-H bonds of alkanes and arenes at rates 50 times higher than does the only previously reported O-donor Ir III complex (see picture). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1540 / 1543

页数：4

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