Aqua(dicyanonitrosomethanido-O)bis(1,10-phenanthroline-N,N′)copper(II) dicyanonitrosomethanide

被引：7

作者：

Miklos, D

Potocnak, I

Dunaj-Jurco, M

Jager, L

机构：

[1] Slovak Univ Technol Bratislava, Dept Inorgan Chem, Bratislava 81237, Slovakia

[2] Univ Halle Wittenberg, Inst Inorgan Chem, D-06120 Halle, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270197010251

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of the title complex, [Cu{ONC(CN)(2)}(C12H8N2)(2)(H2O)][ONC(CN)(2)], is composed of discrete [Cu(dcnm)(H2O)(phen)(2)](+) cations and dcnm anions [phen is 1,10-phenanthroline and dcnm is dicyanonitrosomethanide, ONC(CN)(2)(-)]. The coordination polyhedron of the Cu-II atom is a distorted elongated tetragonal bipyramid with a CuN4O2 chromophore. The water molecule occupies an axial position, while the dcnm anion occupies an equatorial position.

引用

页码：33 / 36

页数：4

共 16 条

[1] STRUCTURE OF BIS(1,10-PHENANTHROLINE)COPPER(II) BIS(HEXAFLUOROPHOSPHATE) [J].