Physical and electroresponsive characteristics of the intercalated styrene-acrylonitrile copolymer/clay nanocomposite under applied electric fields

Styrene-acrylonitrile copolymer (SAN)/clay nanocomposites were synthesized through an emulsion copolymerization of styrene and acrylonitrile in the presence of sodium montmorillonite, and their physical properties and electroresponsiveness under an applied electric field were characterized. Thermogravimetric analysis (TGA) showed that the thermal stability of the synthesized polymer was sustained. X-ray diffraction (XRD) analysis confirmed the insertion of SAN into the interlayers of clay, whose separation consequently increased, as compared to those of the pristine clay. Transmission electron microscopy (TEM) was used to ob serve the suspended state of clay. Dry-base electrorheological (ER) fluids were prepared by mixing intercalated SAN nanocomposite particles into silicone oil. Typical ER behavior, i.e., enhancement of shear and yield stresses in the presence of an applied electric field was observed using a rotational rheometer equipped with, high-voltage generator. A universal yield stress scaling equation was also found to fit our experimental data well. (C) 2003 Wiley Periodicals, Inc.