The crystal field in rare earth based high-temperature superconductors

Neutron spectroscopy is a powerful tool to determine unambiguously the crystal-field (CF) potential in rare-earth (R) based high-T-c superconducting materials. This technique provides detailed information on the electronic ground state of the R ions which is important to understand the thermodynamic magnetic properties as well as the observed coexistence between superconductivity and long-range magnetic ordering of the R ion sublattice at low temperatures. Moreover, the decay of the antiferromagnetic state of the parent compound as well as the evolution of the superconducting state upon doping can be directly and quantitatively monitored. It is found that the observed CF spectra separate into different local components whose spectral weights distinctly depend on the doping level, i.e., there is clear experimental evidence for cluster formation. The onset of superconductivity can be shown to result from percolation which means that the superconductivity is an inhomogeneous materials property. Since the linewidths of CF transitions directly probe the static electronic susceptibility, we discuss temperature-dependent experiments of the relaxation rate of CF excitations in both optimally doped and underdoped regimes. It is shown that there is clear evidence for the opening of an electronic gap in the normal state of underdoped superconductors. Furthermore, the relaxation behavior appears to be extremely dependent upon the energy at which the static susceptibility is being probed. The main observed features can be reproduced by considering a strongly anisotropic gap function.