The crystal structures of Mg3N2 and Zn3N2

被引:156
作者
Partin, DE
Milliams, DJ
OKeeffe, M
机构
[1] Department of Chemistry, Arizona State University, Tempe
基金
美国国家科学基金会;
关键词
D O I
10.1006/jssc.1997.7407
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The structures of Mg3N2 and Zn3N2 have been refined from neutron time-of-flight powder diffraction data. These compounds have the antibixbyite structure and are the first such to be fully refined. The space group is Ia (3) over bar, a = 9.9528(1) Angstrom (Mg3N2) and 9.7691(1) Angstrom (Zn3N2). A revised bond valence parameter for Mg-N bonds is suggested. (C) 1997 Academic Press.
引用
收藏
页码:56 / 59
页数:4
相关论文
共 22 条
[1]  
ANTIC B, 1993, POWDER DIFFR, V0008
[2]   BOND-VALENCE PARAMETERS FOR SOLIDS [J].
BRESE, NE ;
OKEEFFE, M .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197
[3]  
BRESE NF, 1991, STRUCT BOND, V79, P307
[4]  
DAVID J, 1977, B SOC FRANC MIN CRIS, V72, P1949
[5]   Ternary nitrides: A rapidly growing class of new materials [J].
DiSalvo, FJ ;
Clarke, SJ .
CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 1996, 1 (02) :241-249
[6]   Theoretical and experimental investigation of the equations of state and phase stabilities of MgS and CaS [J].
Ekbundit, S ;
Chizmeshya, A ;
LaViolette, R ;
Wolf, GH .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1996, 8 (43) :8251-8265
[7]   NA3AS REVISITED - HIGH-PRESSURE SYNTHESIS OF SINGLE-CRYSTALS AND STRUCTURE REFINEMENT [J].
HAFNER, P ;
RANGE, KJ .
JOURNAL OF ALLOYS AND COMPOUNDS, 1994, 216 (01) :7-10
[8]   On the crystal structures of Zn3N2, Cd3N2 and Ge3N4 -Metal amides and metal nitrides IX. Announcement [J].
Juza, R ;
Hahn, H .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1940, 244 (02) :125-132
[9]  
LARSON AC, 1989, GSAS GEN STRUCTURE A
[10]   STRUCTURE OF ALPHA CALCIUM NITRIDE [J].
LAURENT, Y ;
LANG, J ;
LEBIHAN, MT .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1968, B 24 :494-&