Tuning second-order NLO responses through halogen bonding

被引：109

作者：

Cariati, Elena

Forni, Alessandra

Biella, Serena

Metrangolo, Pierangelo

Meyer, Frank

Resnati, Giuseppe

Righetto, Stefania

Tordin, Elisa

Ugo, Renato

机构：

[1] UdR Milano, Dipartimento CIMA, I-20133 Milan, Italy

[2] UdR Milano, INSTM, I-20133 Milan, Italy

[3] Univ Milan, ISTM CNR, I-20133 Milan, Italy

[4] Politecn Milan, NFMLab, DCMIC G Natta, I-20131 Milan, Italy

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 25期

关键词：

D O I：

10.1039/b702724a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As a function of the ability of the solvent to behave as acceptor of halogen bonding, the NLO-phores under study give rise to mu beta(lambda) values ranging from +192 x 10(-48) esu to -465 x 10(-48) esu.

引用

页码：2590 / 2592

页数：3

共 28 条

[1] A distinctive example of the cooperative interplay of structure and environment in tuning of intramolecular charge transfer in second-order nonlinear optical chromophores [J].

Abbotto, A ;

Beverina, L ;

Bradamante, S ;

Facchetti, A ;

Klein, C ;

Pagani, GA ;

Redi-Abshiro, M ;

Wortmann, R .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (09) :1991-2007

[2] Tuning first molecular hyperpolarizabilities through the use of proaromatic spacers [J].

Andreu, R ;

Blesa, MJ ;

Carrasquer, L ;

Garín, J ;

Orduna, J ;

Villacampa, B ;

Alcalá, R ;

Casado, J ;

Delgado, MCR ;

Navarrete, JTL ;

Allain, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (24) :8835-8845

[3] Hydrogen-bond effects on the electronic absorption spectrum and evaluation of nonlinear optical properties of an aminobenzodifuranone derivative that exhibits the largest positive solvatochromism [J].

Bartkowiak, W ;

Lipkowski, P .

JOURNAL OF MOLECULAR MODELING, 2005, 11 (4-5) :317-322

[4] Inducing structural polarity using fluorinated organics:: X-ray crystal structures of p-XC6F4CN (X = Cl, Br, I) [J].

Bond, AD ;

Griffiths, J ;

Rawson, JM ;

Hulliger, J .

CHEMICAL COMMUNICATIONS, 2001, (23) :2488-2489

[5] CALCULATION OF SMALL MOLECULAR INTERACTIONS BY DIFFERENCES OF SEPARATE TOTAL ENERGIES - SOME PROCEDURES WITH REDUCED ERRORS [J].

BOYS, SF ;

BERNARDI, F .

MOLECULAR PHYSICS, 1970, 19 (04) :553-&

[6] Very large electro-optic responses in H-bonded heteroaromatic films grown by physical vapour deposition [J].

Facchetti, A ;

Annoni, E ;

Beverina, L ;

Morone, M ;

Zhu, PW ;

Marks, TJ ;

Pagani, GA .

NATURE MATERIALS, 2004, 3 (12) :910-917

[7]

Frisch M.J., 2001, GAUSSIAN 98

[8] Cooperativity halogen bonding effect -: Ab initio calculations on H2CO...(C1F)n complexes [J].

Grabowski, Slawomir J. ;

Bilewicz, Elzbieta .

CHEMICAL PHYSICS LETTERS, 2006, 427 (1-3) :51-55

[9] Solvent dependence of the first hyperpolarizability of p-nitroanilines:: Differences between nonspecific dipole-dipole interactions and solute-solvent H-bonds [J].

Huyskens, FL ;

Huyskens, PL ;

Persoons, AP .

JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (19) :8161-8171

[10] Influence of solvent-solute H-bonds of p-nitroanilines on the hyper-Rayleigh scattering in solutions. Preferential environment for non-linear optically active molecules in binary solvent mixtures [J].

Huyskens, FL ;

Huyskens, PL ;

Persoons, A .

JOURNAL OF MOLECULAR STRUCTURE, 1998, 448 (2-3) :161-170

← 1 2 3 →