The first example of direct oxidation of sulfides to sulfones by an osmate molecular oxygen system

被引：47

作者：

Choudary, BM ^{[1
]}

Reddy, CRV ^{[1
]}

Prakash, BV ^{[1
]}

Kantam, ML ^{[1
]}

Sreedhar, B ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 06期

关键词：

D O I：

10.1039/b212749k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Osmate-exchanged Mg-Al layered double hydroxides catalysed the delivery of two oxygen atoms simultaneously via a 3 + 1 cycloaddition to sulfide to form sulfone directly for the first time, reminiscent of 3 + 2 cycloaddition in asymmetric dihydroxylation reactions.

引用

页码：754 / 755

页数：2

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