Low frequency dielectric dispersion of microporous membranes in electrolyte solution

被引:16
作者
Martinsen, OG
Grimnes, S
Karlsen, J
机构
[1] Univ Oslo, Dept Phys, Oslo, Norway
[2] Univ Oslo, Rikshosp, Dept Biomed & Clin Engn, N-0027 Oslo, Norway
[3] Univ Oslo, Dept Pharm, Oslo, Norway
关键词
membranes; pores; dielectric dispersion; counterions; stratum corneum;
D O I
10.1006/jcis.1997.5331
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The electrical properties of microporous membranes in 1 mM KCl solution have been investigated in the frequency range 1 mHz to 1 kHz, using a four-electrode measuring cell, An alpha-dispersion centred around 0.1 Hz was detected and this was assumed to be caused by counterion relaxation effects in the pores of the membrane, Schwarz theory was used to provide a rough estimate on the results to be expected from the measurements. This study is part of a project of which the objective is to reveal the contribution from the electrical properties of the sweat ducts to the total electrical properties of the epidermal stratum corneum, Although the phase angles measured on the membranes were small (<2.9 degrees), more data are needed before any conclusions regarding human skin can be drawn. (C) 1998 Academic Press.
引用
收藏
页码:107 / 110
页数:4
相关论文
共 12 条
[1]   Dispersion and absorption in dielectrics I. Alternating current characteristics [J].
Cole, KS ;
Cole, RH .
JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (04) :341-351
[2]  
FOSTER KR, 1989, CRIT REV BIOMED ENG, V17, P25
[3]  
LIDE R, 1993, CRC HDB CHEM PHYSICS
[4]   ELECTRICAL-PROPERTIES OF AQUEOUS DISPERSIONS OF POLYMER MICROSPHERES [J].
LIM, KH ;
FRANSES, EI .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1986, 110 (01) :201-213
[5]  
MANDEL M, 1984, ANNU REV PHYS CHEM, V35, P75, DOI 10.1146/annurev.physchem.35.1.75
[6]   STREAMING POTENTIAL AS A TOOL IN THE CHARACTERIZATION OF ULTRAFILTRATION MEMBRANES [J].
NYSTROM, M ;
LINDSTROM, M ;
MATTHIASSON, E .
COLLOIDS AND SURFACES, 1989, 36 (03) :297-312
[7]  
Pethig R., 1979, DIELECTRIC ELECT PRO
[8]  
ROSS S, 1988, COLLOID SYSTEMS INTE
[9]  
SCHWAN H P, 1957, Adv Biol Med Phys, V5, P147