Tris(pentafluorophenyl)phosphine complexes of iridium: Molecular structure of trans-IrBr(CO){P(C6F5)(3)}(2)

被引:13
作者
Holloway, JH
Hope, EG
Russell, DR
Saunders, GC
Atherton, MJ
机构
[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,LEICS,ENGLAND
[2] BNFL FLUOROCHEM LTD,PRESTON PR4 0XJ,LANCS,ENGLAND
关键词
D O I
10.1016/0277-5387(95)00209-B
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The first tris(pentafluorophenyl)phosphine complexes of iridium, IrX (CO){P(C6F5)(3)}(2) (X = Cl, Br), formed by the reaction between IrX(3) and P(C6F5)(3) in 2-methoxyethanol, are described and the crystal structure of trans-IrBr(CO) {P(C6F5)(3)}(2) is reported.
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页码:173 / 175
页数:3
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