Triple bonds between heavier Group 14 elements. A theoretical approach

被引：91

作者：

Nagase, S ^{[1
]}

Kobayashi, K ^{[1
]}

Takagi, N ^{[1
]}

机构：

[1] Tokyo Metropolitan Univ, Grad Sch Sci, Dept Chem, Hachioji, Tokyo 1920397, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 611卷 / 1-2期

关键词：

triple bonds; heavier Group 14 elements; substituent effects; disilyne; theoretical study;

D O I：

10.1016/S0022-328X(00)00489-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By providing theoretical insight into the nature of triple bonding between heavier Group 14 elements, the electronic and steric effects of substituents on silicon-silicon triple bonds are investigated to make disilynes synthetically accessible as stable compounds. Synthetic targets worthy of experimental testing are predicted for RSi=SiR. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：264 / 271

页数：8

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