Asymmetric induction with cyclodextrins: Photocyclization of tropolone alkyl ethers

被引：49

作者：

Koodanjeri, S ^{[1
]}

Joy, A ^{[1
]}

Ramamurthy, V ^{[1
]}

机构：

[1] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA

来源：

TETRAHEDRON | 2000年 / 56卷 / 36期

关键词：

host-guest assemblies; cyclodextrins; zeolites;

D O I：

10.1016/S0040-4020(00)00523-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

Employing the photobehavior of tropolone alkyl ethers as the probe, we have established that cyclodextrins could as a serve as a medium to bring about enantioselective photoreactions. The enantioselectivity observed in this study is moderate at best. The enantioselectivity observed in the solid state in comparison to aqueous solution suggests that a rigid environment may be essential to achieve chiral induction during photoreactions of organic molecules. Tn this context the much higher enantioselectivity observed for the same systems within zeolites is noteworthy. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：7003 / 7009

页数：7

共 37 条

[1]

[Anonymous], ADV PHOTOCHEM

[2]

SOLID-STATE PHOTOREACTION OF N,N-DIALKYLPYRUVAMIDES - INCLUSION COMPLEXES WITH DEOXYCHOLIC-ACID OR CYCLODEXTRIN [J].