Efficient resolution of the cis-[Ru(phen)2(MeCN)2]2+ complex (phen=1,10-phenanthroline) using Δ-[tris(tetrachlorobenzenediolato)phosphate(V)] as a chiral counter-ion

被引：15

作者：

Gruselle, M ^{[1
]}

Thouvenot, R

Caspar, W

Boubekeur, K

Amouri, H

Ivanov, M

Tonsuaadu, K

机构：

[1] Univ Paris 06, CNRS, Lab Chim Inorgan & Mat Mol, F-75252 Paris 05, France

[2] Russian State Pedag Univ, Dept Chem, St Petersburg 191186, Russia

[3] Tallinn Univ Technol, Inst Chem Engn, EE-19086 Tallinn, Estonia

来源：

MENDELEEV COMMUNICATIONS | 2004年 / 14卷 / 06期

关键词：

D O I：

10.1070/MC2004v014n06ABEH002034

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of cis-[Ru(phen)(2)(MeCN)(2)] [(Delta)-tris(tetrachlorobenzenediolato)phosphate(V)](2) abbreviated as [1]-[Delta-TRISPHAT](2) and the separation of a mixture of the diastereomeric ion pairs by column chromatography are considered. The X-ray structure of [Delta-1][Delta-TRISPHAT](2) is briefly described, as well as the CD curves of [Delta-1][Delta-TRISPHAT](2) and [Lambda-1][Delta-TRISPHAT](2) fractions.

引用

页码：282 / 283

页数：2

共 22 条

[1] Differentiation of planar chiral enantiomers of [Cp*M(2-alkyl-Phenoxo)] [BF4] {M = Rh, Ir} by the trisphat anion [J].

Amouri, H ;

Thouvenot, R ;

Gruselle, M .

COMPTES RENDUS CHIMIE, 2002, 5 (04) :257-262

[2] Synthesis, NMR, and X-ray molecular structure of a unique chiral propeller-like cobalt complex I(Co2(CO)4)μ,η2,η2-(-H2CC≡CCH2-)(-dppm)2][BF4]2 and differentiation of its enantiomers by the trisphat anion [J].

Amouri, H ;

Thouvenot, R ;

Gruselle, M ;

Malézieux, B ;

Vaissermann, J .

ORGANOMETALLICS, 2001, 20 (10) :1904-1906

[3] APPLICATION OF EXCITON THEORY TO DETERMINATION OF ABSOLUTE CONFIGURATIONS OF INORGANIC COMPLEXES [J].

BOSNICH, B .

ACCOUNTS OF CHEMICAL RESEARCH, 1969, 2 (09) :266-&

[4] ABSOLUTE CONFIGURATIONS OF BIS-BIDENTATE CHELATE COMPOUNDS . CASE OF CIS-BIS(PYRIDINE)BIS(O-PHENANTHROLINE)-RUTHENIUM(2) ION [J].

BOSNICH, B .

INORGANIC CHEMISTRY, 1968, 7 (01) :178-&

[5] BIS-1,10-PHENANTHROLINE COMPLEXES OF DIVALENT RUTHENIUM [J].

BOSNICH, B ;

DWYER, FP .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1966, 19 (12) :2229-&

[6] Enantiospecific synthesis of Λ and Λ [Ru(bPY)2ppy]+ and [Ru(bPY)2quo]+ (bpy=2,2′-bipyridine, ppy = phenylpyridine-H+, quo=8-hydroxyquinolate):: 1H and 13C NMR studies and X-ray structure determination of rac-[Ru(bpy)2quo]PF6 [J].

Brissard, M ;

Convert, O ;

Gruselle, M ;

Guyard-Duhayon, C ;

Thouvenot, R .

INORGANIC CHEMISTRY, 2003, 42 (04) :1378-1385

[7] Resolution and determination of the enantiomeric excesses of hexacoordinated complexes of RuII:: [Ru(bpy)2ppy]+ and [Ru(bpy)2Quo]+ (bpy = bipyridine, ppy = phenylpyridine, Quo = 8-quinolate) used as cationic templates in the formation of three-dimensional anionic networks [J].

Brissard, M ;

Amouri, H ;

Gruselle, M ;

Thouvenot, R .

COMPTES RENDUS CHIMIE, 2002, 5 (01) :53-58

[8]

Brissard M, 2001, EUR J INORG CHEM, P1745

[9]

BRUTLANTS G, 2003, NEW J CHEM, V27, P748

[10]

Caspar R, 2003, EUR J INORG CHEM, P499

← 1 2 3 →