Controlled release of guest molecules from mesoporous silica particles based on a pH-responsive polypseudorotaxane motif

被引:398
作者
Park, Chiyoung
Oh, Kyoungho
Lee, Sang Cheon
Kim, Chulhee [1 ]
机构
[1] Inha Univ, Dept Polymer Sci & Engn, Hyperstructured Organ Mat Res Ctr, Inchon 402751, South Korea
[2] Korea Inst Ceram Engn & Technol, Nanomat Applicat Div, Seoul 153801, South Korea
关键词
cyclodextrins; host-guest systems; mesoporous materials; rotaxanes; supramolecular chemistry;
D O I
10.1002/anie.200603404
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Stringing them along: The pores of a mesoporous silica particle were filled with guest molecules and then blocked by threading cyclodextrin molecules (CDs) onto the surface-grafted polyethylenimine (PEI) chains at pH 11. At pH 5.5, the guest molecules can be released from the pores of the particle by reversible dethreading of the CDs from the PEI chains. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:1455 / 1457
页数:3
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